CAJ | 학술논문

毛细管电色谱(CEC)作为一种新型微柱分离技术,具有高效、高选择性、高分辨率和快速分离等特点.由于CEC进样体积通常为纳升级,所以对检测系统的高灵敏检测提出了很高的要求.当前,发展CEC与各种高灵敏检测器的联用已成为CEC研究中最活跃的方向之一.本文简要介绍了CEC研究的发展历程,系统综述了CEC与各类检测器联用技术及其在复杂样品分离分析中应用的最新进展,并对CEC联用技术的前景进行了展望.引用文献141篇.
모세관전색보(CEC)작위일충신형미주분리기술,구유고효、고선택성、고분변솔화쾌속분리등특점.유우CEC진양체적통상위납승급,소이대검측계통적고령민검측제출료흔고적요구.당전,발전CEC여각충고령민검측기적련용이성위CEC연구중최활약적방향지일.본문간요개소료CEC연구적발전역정,계통종술료CEC여각류검측기련용기술급기재복잡양품분리분석중응용적최신진전,병대CEC련용기술적전경진행료전망.인용문헌141편.
As a novel micro-separation technique,capillary electrochromatography (CEC) has the merits of high efficiency,high selectivity,high resolution and rapid analysis.However,the small-volume injection manipulated in capillary dimensions poses a great challenge for detectors in achieving high sensitivity.Currently,one of the major researches into CEC involves the development of some sensitive detection modes.The general introduction,which includes the historical perspectives and the principles of CEC,is briefly described.The recent advances about CEC coupled with various detectors and its applications in the separation of complex samples are summarized.A total of 141 references are reviewed.