CAJ | 학술논문

用P2S5分别与萘和二茂铁反应，得到两种配位基前体：(L1，C10H7为naphthyl萘基)和(L2，Fc为二茂铁基).L1和L2分别与Co2(CO)8反应，得到两种新的含S、P桥基的六核钴羰基簇合衍生物：Co6(μ3-S)2(μ4,η2-SPC10H7)(CO)14(Ⅰ)和Co6(μ3-S)2(μ4,η2-SPFc)(CO)14(Ⅱ).L1与Ru3(CO)12反应得到Ru3(μ3-S)(μ-H)2(CO)9(Ⅲ)和Ru4(μ3-S)(μ3-PC10H7)(CO)10(Ⅳ).通过元素分析和谱学表征，对簇合物Ⅰ～Ⅳ的结构进行了推测.
용P2S5분별여내화이무철반응，득도량충배위기전체：(L1，C10H7위naphthyl내기)화(L2，Fc위이무철기).L1화L2분별여Co2(CO)8반응，득도량충신적함S、P교기적륙핵고탄기족합연생물：Co6(μ3-S)2(μ4,η2-SPC10H7)(CO)14(Ⅰ)화Co6(μ3-S)2(μ4,η2-SPFc)(CO)14(Ⅱ).L1여Ru3(CO)12반응득도Ru3(μ3-S)(μ-H)2(CO)9(Ⅲ)화Ru4(μ3-S)(μ3-PC10H7)(CO)10(Ⅳ).통과원소분석화보학표정，대족합물Ⅰ～Ⅳ적결구진행료추측.
The reaction of Co2(CO)8 with the ligand precusors ( L1，naphthylC10H7) and (L2，ferrocenyl Fc) yields two hexanuclear cobalt carbonyl cluster derivatives Co6(μ3-S)2(μ4,η2-SPC10H7(CO)14(Ⅰ)and Co6(μ3-S)2(μ4,η2-SPFc)(CO)14(Ⅱ)respectively. The reaction of Ru3(CO)12 with L1 gives a three nuclear ruthenium carbonyl cluster derivative Ru3(μ3-S)(μ-H)2(CO)9 (Ⅲ)and a four nuclear cluster Ru4(μ3-S)(μ3-PC10H7)(CO)10(Ⅳ)simultaneously. The clusters Ⅰ～Ⅳ are characterized by elementary analysis, IR(co)、1 HNM0 and MS Spectroscopy, which shows that three of the four clusters are novel compounds.