无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2005年
2期
217-220
,共4页
周泊%史发年%王静梅%陈民勤
週泊%史髮年%王靜梅%陳民勤
주박%사발년%왕정매%진민근
有机-无机杂合物%钒氧化物%水热合成%晶体结构
有機-無機雜閤物%釩氧化物%水熱閤成%晶體結構
유궤-무궤잡합물%범양화물%수열합성%정체결구
organic-inorganic hybrid%vanadium oxides%hydrothermal synthesis%crystal structure
A novel compound Ni (phen)(H2O)(V2O6) has been hydrothermally synthesized and structurally determined to be a two-dimensional compound, which contains {V2O6}n2n- chains interconnected by nickel(Ⅱ) complexes via oxygen atoms. The crystallographic data measured by single-crystal X-ray diffraction analysis are as follows:C12H10N2NiO7V2, Mr=454.81, monoclinic, space group P21/c, a=0.784 6(3), b=2.103 6(8), c=0.942 3(4) nm,β=flections collected, 2 470 independent (Rint=0.032 2), the final R=0.058 4 and wR2=0.145 7 for 2 303 observed reflections with I＞2σ(I). CCDC: 192520.
