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无机化学学报 무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2004年 8期 1001-1004 ,共4页

陈宏基陳宏基

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1,10-邻啡啰啉5,6-双(水扬醛)亚氨%希夫碱%双核配合物 1,10-鄰啡啰啉5,6-雙(水颺醛)亞氨%希伕堿%雙覈配閤物
1,10-린배라람5,6-쌍(수양철)아안%희부감%쌍핵배합물
N,N'-Bis(salicyidene)-5,6-phenanthrolinenediamine Schiff base binuclear complex

A new ligand N, N'-Bis(salicyidene)-5,6-phenanthrolinenediamine (H2L) 1 and its four binuclear complexes [M2+LM2+(B-)2](M=Cu2+, B-=Ac-, 1a; M=Ni2+, B-=Ac-, 1b; M=Co2+, B-=Cl-, 1c; M=Ni2+, B-=Cl-, 1d) have been prepared by condensing 1 equiv, of 5,6-diamino-1,10-Phenanthroline with 2 equiv, of 2-hydroxybenzaldehyde and reaction of 1 with metal salts, and characterized by IR, 1H and 13C NMR, UV-Vis and EI-MS analysis.