中国有色金属学会会刊(英文版)
中國有色金屬學會會刊(英文版)
중국유색금속학회회간(영문판)
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
2004年
2期
232-236
,共5页
袁志庆%吕光烈%顾建明%屠小燕%王新喜
袁誌慶%呂光烈%顧建明%屠小燕%王新喜
원지경%려광렬%고건명%도소연%왕신희
in-situ X-ray diffraction%phase transformation%lattice expansion%intermetallic alloys%hydrides
Phase transformations and lattice expansions of M1Ni3.75 Co0.75 Mn0.3 Al0.2 during the electrochemical hydriding-dehydriding process were investigated using in-situ X-ray diffraction. An intermediate hydride γ phase between the hydrogen solid solution a phase and fully hydrided β phase can be observed during the cycling. The formation of γ phase is related to the diffusion of hydrogen in the crystal grains. The lower the charge rate is, the higher the content of γ phase is. The phase transformations during the hydriding-dehydriding process can be described as α(→←)α+γ+β(→←)β(→←)γ+α(→←)α. The lattice expansion from a toβ is discrete, while that from γ to β is continuous. The formation of γ phase can reduce the discrete lattice expansion from a toβ by 30 %.
