CAJ | 학술논문

采用垂直沉积技术及相应的改进方法,使用化学合成的400 nm单分散二氧化硅微球自组装制备了胶体晶体薄膜.通过扫描电镜与分光光度计对样品的微观结构与透过光谱进行了表征,并对比研究了不同的垂直沉积方法对胶体晶体的影响.结果表明,通过温度与流量控制两种改进手段,均能制备具有六方密堆结构周期排列的胶体晶体薄膜.在垂直沉积过程中适当的升高温度有利于降低胶体粒子的用量,而通过流量控制的垂直沉积技术则可以有效缩短自组装时间.通过调节蠕动泵改变液面与基板的相对运动速度,或者调控温度改变胶体溶液的蒸发速率,可在材料表面形成单层或多层的胶体晶体薄膜.改进的垂直沉积技术将有望应用于快速沉积大面积、高质量的胶体晶体材料.
채용수직침적기술급상응적개진방법,사용화학합성적400 nm단분산이양화규미구자조장제비료효체정체박막.통과소묘전경여분광광도계대양품적미관결구여투과광보진행료표정,병대비연구료불동적수직침적방법대효체정체적영향.결과표명,통과온도여류량공제량충개진수단,균능제비구유륙방밀퇴결구주기배렬적효체정체박막.재수직침적과정중괄당적승고온도유리우강저효체입자적용량,이통과류량공제적수직침적기술칙가이유효축단자조장시간.통과조절연동빙개변액면여기판적상대운동속도,혹자조공온도개변효체용액적증발속솔,가재재료표면형성단층혹다층적효체정체박막.개진적수직침적기술장유망응용우쾌속침적대면적、고질량적효체정체재료.
The fabrication and characterization of silica colloidal crystal films self-assembled from suspension of monodisperse silica spheres are reported through different improvement on vertical deposition. Three vertical deposition methods on the crystal formation were compared in terms of microstructure and optical transmission measurements. The results show that both the temperature-controlled vertical deposition and the flow-controlled vertical deposition could gain closely packed structures as traditional method but with lower colloid consumption and shorter time of self-assembly. By adjusting the rate of solvent evaporation or the relative movement between the liquid-surface and substrate, it is possible to transfer monolayer or multilayer of silica colloidal crystals onto the substrates. The improved methods can be used for rapid deposition of high-quality colloidal crystal films over large surface area without any special equipment.