南昌大学学报(理科版)
南昌大學學報(理科版)
남창대학학보(이과판)
JOURNAL OF NANCHANG UNIVERSITY(NATURAL SCIENCE)
2009年
5期
499-504
,共6页
彭希珑%何宗健%刘小真%金腊华
彭希瓏%何宗健%劉小真%金臘華
팽희롱%하종건%류소진%금석화
源解析%多环芳烃%PM_(2.5)
源解析%多環芳烴%PM_(2.5)
원해석%다배방경%PM_(2.5)
source apportionment%PAHs%PM_(2.5)
在南昌市布设5个采样点,代表交通干线区、工业区、商业区、居民区以及郊区,于2007年进行气溶胶PM_(2.5)的采样.各采样点测得的数据表明,PM_(2.5)中多环芳烃浓度呈现出夏低冬高的特征,空间分布上,南昌市PM_(2.5)中多环芳烃污染情况为交通干线>工业区>商业区>居民区>郊区,基于这些检测数据,通过因子分析法中的主成分分析法判断PM_(2.5)中多环芳烃的主要来源,利用多元逐步回归法确定各主要污染源对多环芳烃的贡献率.结果表明南昌市的主要污染源车辆排放源(标识物苯并(g,h,i)苝)、燃煤污染源(标识物荧蒽)、焦化污染源(标识物苯并(k)荧蒽)和高温加热源(标识物菲)对南昌市大气PM_(2.5)中多环芳烃的贡献率分别为31.0%、21.1%、25.8%和(14.6%).
在南昌市佈設5箇採樣點,代錶交通榦線區、工業區、商業區、居民區以及郊區,于2007年進行氣溶膠PM_(2.5)的採樣.各採樣點測得的數據錶明,PM_(2.5)中多環芳烴濃度呈現齣夏低鼕高的特徵,空間分佈上,南昌市PM_(2.5)中多環芳烴汙染情況為交通榦線>工業區>商業區>居民區>郊區,基于這些檢測數據,通過因子分析法中的主成分分析法判斷PM_(2.5)中多環芳烴的主要來源,利用多元逐步迴歸法確定各主要汙染源對多環芳烴的貢獻率.結果錶明南昌市的主要汙染源車輛排放源(標識物苯併(g,h,i)苝)、燃煤汙染源(標識物熒蒽)、焦化汙染源(標識物苯併(k)熒蒽)和高溫加熱源(標識物菲)對南昌市大氣PM_(2.5)中多環芳烴的貢獻率分彆為31.0%、21.1%、25.8%和(14.6%).
재남창시포설5개채양점,대표교통간선구、공업구、상업구、거민구이급교구,우2007년진행기용효PM_(2.5)적채양.각채양점측득적수거표명,PM_(2.5)중다배방경농도정현출하저동고적특정,공간분포상,남창시PM_(2.5)중다배방경오염정황위교통간선>공업구>상업구>거민구>교구,기우저사검측수거,통과인자분석법중적주성분분석법판단PM_(2.5)중다배방경적주요래원,이용다원축보회귀법학정각주요오염원대다배방경적공헌솔.결과표명남창시적주요오염원차량배방원(표식물분병(g,h,i)패)、연매오염원(표식물형은)、초화오염원(표식물분병(k)형은)화고온가열원(표식물비)대남창시대기PM_(2.5)중다배방경적공헌솔분별위31.0%、21.1%、25.8%화(14.6%).
Five sampling areas which represent traffic center,industrial area,commercial area,residential area and the suburb,were set in Nanchang city to collect fine particulate matter in ambient air of 2007.The determined data at various sampling areas illustrated that the polycyclic aromatic hydrocarbons (PAHs) concentration of PM_(2.5) in summer were lower than that in winter.In different areas the pollution severity order of PM_(2.5) was traffic center(worse than),industrial area,commercial area,residential area and suburb.Based on the data,the main sources of PAHs on fine particulate matter (PM_(2.5)) in Nanchang city were estimated by principal component analysis method of factor analysis method.The percentage of contributions of various pollution source to PAHs on fine particulate matter in Nanchang city were calculated by multiple linear stepwise analysis method.The main pollution sources were vehicle emission (identification was benzo(ghi)perylene),coal burning(identification was fluoranthene),high-temperature combustion(identification was benzo(k)fluoranthene) and coking pollution(identification was phenanthren) to PAHs in PM_(2.5) which accounted for 31.0%、21.1%、25.8% and 14.6%.