分析化学
分析化學
분석화학
CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
2001年
6期
682-684
,共3页
邹长英%张红%徐变珍
鄒長英%張紅%徐變珍
추장영%장홍%서변진
乳状液膜%氯化三辛基·甲基铵%谷氨酸%迁移行为
乳狀液膜%氯化三辛基·甲基銨%穀氨痠%遷移行為
유상액막%록화삼신기·갑기안%곡안산%천이행위
用氯化三辛基·甲基铵(Aliquat 336)Span80甲
苯制成的乳状液膜体系对谷氨酸的迁移行为进行了研究,2 min的迁移率可达93%。在谷氨酸的最佳迁移条件下,油溶性好的苯丙氨酸迁移率较高,但油溶性低的甘氨酸和碱性氨基酸的迁移率明显较低。此法适用于微量氨基酸的提取和分离。
用氯化三辛基·甲基銨(Aliquat 336)Span80甲
苯製成的乳狀液膜體繫對穀氨痠的遷移行為進行瞭研究,2 min的遷移率可達93%。在穀氨痠的最佳遷移條件下,油溶性好的苯丙氨痠遷移率較高,但油溶性低的甘氨痠和堿性氨基痠的遷移率明顯較低。此法適用于微量氨基痠的提取和分離。
용록화삼신기·갑기안(Aliquat 336)Span80갑
분제성적유상액막체계대곡안산적천이행위진행료연구,2 min적천이솔가체93%。재곡안산적최가천이조건하,유용성호적분병안산천이솔교고,단유용성저적감안산화감성안기산적천이솔명현교저。차법괄용우미량안기산적제취화분리。
The transport of glutamic acid through the surfactant liq uid membrane of trioctyl (mono) methyl ammonium chloride(Aliquat336)Span 80-toluene has been studied. The optimal experimental conditions for transport of gl
utamic acid with high efficiency and high speed were obtained. The conditions we
re that membrane phase was 0.020 mol/L Aliquat 336+3%(W/V)Span80+Tolu
ene; Outer phase was 5×10-4 mol/L glutamic acid and Ph=9.3;Inner pha
se was 0.05 mol/L HCl. The transport rate of glutamic acid reached 93% in 2 min
of transport time. The phenylalanine was also transported at the optimal transpo
rt conditions of glutamic acid. The transport rates of Glycine and basic amino a
cids were lower. This method can be used for extraction and separation of micro
amount of amino acids.