无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2012年
8期
1736-1742
,共7页
周先礼%张秉君%王萃娟%黄帅%邱光美%王尧宇
週先禮%張秉君%王萃娟%黃帥%邱光美%王堯宇
주선례%장병군%왕췌연%황수%구광미%왕요우
1,1'-(1,4-丁二基)双咪唑%配位聚合物%荧光光谱%抑菌性
1,1'-(1,4-丁二基)雙咪唑%配位聚閤物%熒光光譜%抑菌性
1,1'-(1,4-정이기)쌍미서%배위취합물%형광광보%억균성
1,1'-(1,4-Butanediyl)bis(imidazole)%coordination polymer%fluorescence spectrum%antimicrobial activity
本文报道了一个基于双咪唑配体的锌配位聚合物[Zn(oxa)(bbi)]n (1)(oxa=草酸,bbi=1,1'-(1,4-丁二基)双咪唑),并对该化合物进行元素分析、红外和X-射线单晶衍射分析.结果表明标题化合物通过配位键和π-π堆积作用力形成了一个由(4,4)拓扑形状的二维网络组成的具有大孔洞的三维金属有机框架结构.除此之外,测定了配合物1的荧光发射光谱并对其微生物抑菌性能进行了初步研究.
本文報道瞭一箇基于雙咪唑配體的鋅配位聚閤物[Zn(oxa)(bbi)]n (1)(oxa=草痠,bbi=1,1'-(1,4-丁二基)雙咪唑),併對該化閤物進行元素分析、紅外和X-射線單晶衍射分析.結果錶明標題化閤物通過配位鍵和π-π堆積作用力形成瞭一箇由(4,4)拓撲形狀的二維網絡組成的具有大孔洞的三維金屬有機框架結構.除此之外,測定瞭配閤物1的熒光髮射光譜併對其微生物抑菌性能進行瞭初步研究.
본문보도료일개기우쌍미서배체적자배위취합물[Zn(oxa)(bbi)]n (1)(oxa=초산,bbi=1,1'-(1,4-정이기)쌍미서),병대해화합물진행원소분석、홍외화X-사선단정연사분석.결과표명표제화합물통과배위건화π-π퇴적작용력형성료일개유(4,4)탁복형상적이유망락조성적구유대공동적삼유금속유궤광가결구.제차지외,측정료배합물1적형광발사광보병대기미생물억균성능진행료초보연구.
A coordination polymer based on zinc(Ⅱ) and mixed ligands [Zn(oxa)(bbi)]n (1) (oxa=oxalate anion,bbi=1,1'-(1,4-butanediyl)bis (imidazole)),has been prepared and characterized by single-crystal X-ray diffraction.The structure of polymer 1 presents an unique two-dimensional (2D) layer structure with (4,4) topology in the presence of meso-helical chains and a three-dimensional (3D) network distorted with large channels.In addition,moderate fluorescent emission in the solid state at room temperature was observed in the Zn1-containing polymeric compound 1.And antimicrobial activity of the compound has been investigated.CCDC:842497.
