CAJ | 학술논문

设计并合成了含有多个取代基的苯乙炔衍生物（0EDHPA）单体，并在不同的催化体系中，对单体的螺旋聚合反应条件进行的研究，结果显示含有多个取代基的苯乙炔衍生物单体OEDHPA在以铑络合物[Rh（nbd）C1]：为催化剂，手性胺（R）-PEA或（S）-PEA为共催化剂的手性催化体系中进行了螺旋聚合，并通过1HNMR、IR及元素分析确定了单体的结构，利用圆二色谱一紫外光谱（CD—UV）确认了生成聚合物的螺旋结构。最后在不同的溶剂中，对聚合而成的螺旋高分子的溶解性进行了考察。
설계병합성료함유다개취대기적분을결연생물（0EDHPA）단체，병재불동적최화체계중，대단체적라선취합반응조건진행적연구，결과현시함유다개취대기적분을결연생물단체OEDHPA재이로락합물[Rh（nbd）C1]：위최화제，수성알（R）-PEA혹（S）-PEA위공최화제적수성최화체계중진행료라선취합，병통과1HNMR、IR급원소분석학정료단체적결구，이용원이색보일자외광보（CD—UV）학인료생성취합물적라선결구。최후재불동적용제중，대취합이성적라선고분자적용해성진행료고찰。
We design and synthesized 4-{4-（ 2-Octyloxyethylaminomethyl ）benzyloxy}-3,5-bis（ hydroxyl-methyl ） phenylacetylene （ OEDHPA ） successfully. Discuss the polymerization of OEDHPA in the achiral and chiral catalytic system and get the results that the polymerization initiated by the catalytic system consisting of Rhodium complex and chiral amine （R）-PEA or （S）-PEA can provide one-hand helical polymer. We confirmed the structure of the monomer through the NMR and IR spectra and the helical structure of the polymer by the CD-UV spectra. Then the solubility of the resulting one-hand helical polymer in different solvent were confirmed in the last part of this paper.