造纸化学品
造紙化學品
조지화학품
PAPER CHEMICALS
2011年
5期
20-24
,共5页
陈金龙%张秀梅%苗聪%金杭
陳金龍%張秀梅%苗聰%金杭
진금룡%장수매%묘총%금항
不饱和聚合物%湿强剂%环氧基团%紫外固化
不飽和聚閤物%濕彊劑%環氧基糰%紫外固化
불포화취합물%습강제%배양기단%자외고화
unsaturated polymer%wet strength agent%epoxy group%uv-curing
该文以苯乙烯、甲基丙烯酸缩水甘油酯和异戊二烯为原料,合成了具有不饱和碳碳双键、环氧基团等活性基团的不饱和造纸湿强树脂,利用傅立叶-拉曼光谱分析仪分析产物的结构,利用扫描电镜观测纸页经紫外固化后成纸纤维与湿强剂的交联情况,探讨紫外固化对纸页强度性能的影响。研究表明,相对于自然光固化,紫外固化后纸页的湿强性能提升更大;添加了湿强树脂的纸页经2 min紫外固化后,其湿强指数相对于无紫外固化的纸页提高了223%,湿强保留率达到25.8%。
該文以苯乙烯、甲基丙烯痠縮水甘油酯和異戊二烯為原料,閤成瞭具有不飽和碳碳雙鍵、環氧基糰等活性基糰的不飽和造紙濕彊樹脂,利用傅立葉-拉曼光譜分析儀分析產物的結構,利用掃描電鏡觀測紙頁經紫外固化後成紙纖維與濕彊劑的交聯情況,探討紫外固化對紙頁彊度性能的影響。研究錶明,相對于自然光固化,紫外固化後紙頁的濕彊性能提升更大;添加瞭濕彊樹脂的紙頁經2 min紫外固化後,其濕彊指數相對于無紫外固化的紙頁提高瞭223%,濕彊保留率達到25.8%。
해문이분을희、갑기병희산축수감유지화이무이희위원료,합성료구유불포화탄탄쌍건、배양기단등활성기단적불포화조지습강수지,이용부립협-랍만광보분석의분석산물적결구,이용소묘전경관측지혈경자외고화후성지섬유여습강제적교련정황,탐토자외고화대지혈강도성능적영향。연구표명,상대우자연광고화,자외고화후지혈적습강성능제승경대;첨가료습강수지적지혈경2 min자외고화후,기습강지수상대우무자외고화적지혈제고료223%,습강보류솔체도25.8%。
Styrene(St),glycidyl methacrylate(GMA) and isoprene were used to prepare an unsaturated wet strength agent which contains some reactive groups such as carbon-carbon double bonds and epoxy groups.Fourier-Raman spectrometer was used to analyze the structure of the polymer.SEM was used to observe the crosslinking of fibers and the wet strength polymers.The results showed that compared to the natural light curing,UV-curing gave better strength properties of handsheets,as it can been that 2 minutes UV-curing increased the wet tensile index of handsheets by 223%,and the wet strength retention ratio was as high as 25.8%.