石油化工腐蚀与防护
石油化工腐蝕與防護
석유화공부식여방호
PETROCHEMICAL CORROSION AND PROTECTION
2011年
3期
22-24
,共3页
黄起中%付强%邵三多%曹学丰
黃起中%付彊%邵三多%曹學豐
황기중%부강%소삼다%조학봉
超高压%反应管%腐蚀%水质控制%改造
超高壓%反應管%腐蝕%水質控製%改造
초고압%반응관%부식%수질공제%개조
super high pressure%reactor tube%corrosion%water quality control%revamp
由于塑料厂LDPE(高压低密度聚乙烯)装置反应管换热水水质指标设计上不严格,没有按照锅炉水管理,没有微量氧、铁离子和硬度等指标要求,且设计上只有联氨药剂除氧措施,缺少必要的水质控制和处理措施。多年来,装置水质一直不合格,微量氧、硬度、pH值、铁离子等指标超标,出现了水系统结垢、腐蚀和混浊等现象,发生了设备锈蚀、管路腐蚀以及换热器结垢等问题。为了消除由于腐蚀、结垢而造成的水泵机封损坏、超高压反应管缝隙腐蚀等问题,有针对性地进行了防止腐蚀改善水质的除氧剂、pH值调整剂、硬度消除和垢分散剂加入等改造,取得了良好的效果。
由于塑料廠LDPE(高壓低密度聚乙烯)裝置反應管換熱水水質指標設計上不嚴格,沒有按照鍋爐水管理,沒有微量氧、鐵離子和硬度等指標要求,且設計上隻有聯氨藥劑除氧措施,缺少必要的水質控製和處理措施。多年來,裝置水質一直不閤格,微量氧、硬度、pH值、鐵離子等指標超標,齣現瞭水繫統結垢、腐蝕和混濁等現象,髮生瞭設備鏽蝕、管路腐蝕以及換熱器結垢等問題。為瞭消除由于腐蝕、結垢而造成的水泵機封損壞、超高壓反應管縫隙腐蝕等問題,有針對性地進行瞭防止腐蝕改善水質的除氧劑、pH值調整劑、硬度消除和垢分散劑加入等改造,取得瞭良好的效果。
유우소료엄LDPE(고압저밀도취을희)장치반응관환열수수질지표설계상불엄격,몰유안조과로수관리,몰유미량양、철리자화경도등지표요구,차설계상지유련안약제제양조시,결소필요적수질공제화처리조시。다년래,장치수질일직불합격,미량양、경도、pH치、철리자등지표초표,출현료수계통결구、부식화혼탁등현상,발생료설비수식、관로부식이급환열기결구등문제。위료소제유우부식、결구이조성적수빙궤봉손배、초고압반응관봉극부식등문제,유침대성지진행료방지부식개선수질적제양제、pH치조정제、경도소제화구분산제가입등개조,취득료량호적효과。
As there was no strict control on the water quality for the super HP reactor heat exchange tubes in design, the water specifications were not controlled as those for the boiler feed water, there were no requirements on trace oxygen, Fe ions and hardness and there are no water quality control and water treatment measures, the water quality has been off specifications for many years in trace oxygen, hardness, pH value and Fe ions, etc. As the result, serious fouling, corrosion and turbidness have occurred in the water system, and equipment and piping and heat exchanger are subject to corrosion and fouling. To prevent the failure of mechanical seal of water pumps due to corrosion and fouling and crevice corrosion of super HP reactor heat exchange tubes, the plant has been revamped for addition of de - aeration agent, pH adjustment additive, hardness reduction agent and dispersant, etc, and good results have been achieved.