CAJ | 학술논문

以环氧树脂为炭质前驱体将TiO2粉体粘附于ACF表面,然后在N2气氛460 ℃焙烧,树脂热解、逸失使剩余残炭成为二者之间的连接体,获得TiO2/ACF复合产品.ACF负载TiO2后,其比表面积降低,但仍很好地维持了ACF的孔隙结构.由SEM可知,纳米级单体TiO2颗粒以微小团簇结构分布于ACF表面.以对氨基苯酚、亚甲基兰和β-环状糊精三种不同分子尺寸的有机化合物为探针,通过TiO2/ACF对它们的光催化降解研究发现,化合物自身分子尺寸对其降解程度有重要影响.具有适宜分子尺寸亚甲基兰的去除程度最高,TiO2/ACF的降解速率高于悬浮态P25,在重复利用过程中未见降低.通过对比三种有机分子在有、无紫外光照下的去除程度,可确认有机分子是被降解而非吸附于TiO2/ACF上.
이배양수지위탄질전구체장TiO2분체점부우ACF표면,연후재N2기분460 ℃배소,수지열해、일실사잉여잔탄성위이자지간적련접체,획득TiO2/ACF복합산품.ACF부재TiO2후,기비표면적강저,단잉흔호지유지료ACF적공극결구.유SEM가지,납미급단체TiO2과립이미소단족결구분포우ACF표면.이대안기분분、아갑기란화β-배상호정삼충불동분자척촌적유궤화합물위탐침,통과TiO2/ACF대타문적광최화강해연구발현,화합물자신분자척촌대기강해정도유중요영향.구유괄의분자척촌아갑기란적거제정도최고,TiO2/ACF적강해속솔고우현부태P25,재중복이용과정중미견강저.통과대비삼충유궤분자재유、무자외광조하적거제정도,가학인유궤분자시피강해이비흡부우TiO2/ACF상.
TiO2 was supported on activated carbon fibers (ACF) with utilization of epoxy resin as the precursor of adhesive coating, followed by calcination at 460 ℃ in nitrogen atmosphere. As TiO2 was loaded on ACF, the specific surface area of the supported catalyst (TiO2/ACF) decreased, but the pore structure of ACF was well preserved. From SEM images, it was observed that TiO2 distributed on ACF in the form of small clusters with the size of primary particles in nanometer. The photocatalytic degradations of three organic compounds with different molecular sizes, i.e. p-aminophenol, methylene blue and β-cyclodextrin were investigated. The results showed that the molecular size of organic compound had an important effect on its degradation over TiO2/ACF catalyst. The highest efficiency of degradation can be obtained only when methylene blue molecules with moderate size was employed in the reaction. Furthermore, the rate of photodegradation was higher than that when the suspended P25 was used as photocatalyst without any decline for repeating use. By comparison the amounts of three organic compounds removal with and without UV irradiation, it was confirmed that the compounds were degraded instead of being adsorbed on TiO2/ACF.