中国化学快报(英文版)
中國化學快報(英文版)
중국화학쾌보(영문판)
CHINESE CHEMICAL LETTERS
2006年
3期
293-295
,共3页
Suzuki coupling reaction%core functionalization%carbosilane%dendrimer%naphthalene
Carbosilane dendrimers with p-bromophenyl core were synthesized by alternating Grignard and hydrosilylation reaction. And the α-naphthalenyl was connected to the core by the Suzuki coupling reaction. A new carbosilane dendrimer with big π-conjugated structure[4-(naphthalen-1-yl)phenyl core] was given. It shows Suzuki coupling reaction is an effective and powerful core-functionalization method and the satisfactory result can be obtained through prolonging the reaction time with the increase of the generation of dendrimer.