西安交通大学学报
西安交通大學學報
서안교통대학학보
JOURNAL OF XI'AN JIAOTONG UNIVERSITY
2001年
4期
382-384,389
,共4页
王琪琨%刘卫华%窦菊英%朱长纯
王琪琨%劉衛華%竇菊英%硃長純
왕기곤%류위화%두국영%주장순
奇异碳纳米管%放电%生长%封闭
奇異碳納米管%放電%生長%封閉
기이탄납미관%방전%생장%봉폐
用电弧法制备碳纳米管时,在阴极沉积物中,伴随大量正常的离散碳纳米管的产生,发现了孪生碳纳米管、菱形碳纳米管、“Y”形短管和碳纳米纤维等几种奇异的碳纳米形态.给出了这些奇异碳纳米管的透射电镜(TEM)照片,对它们的生长、闭合过程进行了研究,认为碳原子流、电场等因素的影响是奇异碳纳米管形成的关键,借助碳纳米管以内层为模板的开口生长模型,可以定性地理解它们的形成过程及生长机理.
用電弧法製備碳納米管時,在陰極沉積物中,伴隨大量正常的離散碳納米管的產生,髮現瞭孿生碳納米管、蔆形碳納米管、“Y”形短管和碳納米纖維等幾種奇異的碳納米形態.給齣瞭這些奇異碳納米管的透射電鏡(TEM)照片,對它們的生長、閉閤過程進行瞭研究,認為碳原子流、電場等因素的影響是奇異碳納米管形成的關鍵,藉助碳納米管以內層為模闆的開口生長模型,可以定性地理解它們的形成過程及生長機理.
용전호법제비탄납미관시,재음겁침적물중,반수대량정상적리산탄납미관적산생,발현료련생탄납미관、릉형탄납미관、“Y”형단관화탄납미섬유등궤충기이적탄납미형태.급출료저사기이탄납미관적투사전경(TEM)조편,대타문적생장、폐합과정진행료연구,인위탄원자류、전장등인소적영향시기이탄납미관형성적관건,차조탄납미관이내층위모판적개구생장모형,가이정성지리해타문적형성과정급생장궤리.
Among the large quantities of normal carbon nanotubes there are some odd carobon nanotubes in a cathode deposit obtained by arc discharge, such as double-tube, diamond-tube, Y-shaped tube ect.The TEM images of these odd carbon nanotubes are presented,and their growth and closure processes with the opening end growth model of carbon nantubes are studied.Carbon atoms current, electric field and other factors can effect on the formation of odd carbon nanotubes.The mechanism of their growth can be qualitatively explained by the carbon nanotubes growth theory.