CAJ | 학술논문

实验研究在碱性和酸性条件下过二硫酸钾高温氧化四种不同类型含磷标准化合物在海水中的回收率和影响回收率的因素。结果表明：在碱性条件下过二硫酸钾高温氧化可使海水中非聚磷类化合物完全回收，而聚磷类化合物回收率不高，延长消化时间聚磷类化合物的回收率有一定提高。除个别化合物外，各类含磷化合物在酸性条件下可被定量回收。依此，建立酸性过硫酸盐氧化法分解测定海水中溶解态总磷的方法。
실험연구재감성화산성조건하과이류산갑고온양화사충불동류형함린표준화합물재해수중적회수솔화영향회수솔적인소。결과표명：재감성조건하과이류산갑고온양화가사해수중비취린류화합물완전회수，이취린류화합물회수솔불고，연장소화시간취린류화합물적회수솔유일정제고。제개별화합물외，각류함린화합물재산성조건하가피정량회수。의차，건립산성과류산염양화법분해측정해수중용해태총린적방법。
Experimental studies have been conducted on the decomposit ionefficiency of four different types of organic and inorganic phosphorus compo unds in seawater under acid or basic condition by persulphate oxidation. The inf luence factors on decomposition efficiency, such as digestion time and pH were i dentified. It was shown that non-condensed phosphate could be decomposed comple tely by persulphate. But in alkali condition, condensed phosphate can only be de composed partly. Almost 100% decomposition efficiency could be reached for all t ypes of compounds containing phosphorus under acid condition. A persulphate oxid ation method in acid medium for decomposition and analysis of dissolved total ph osphorus in seawater was proposed.