塑料工业
塑料工業
소료공업
CHINA PLASTICS INDUSTRY
2001年
1期
26-27,38
,共3页
张明耀%徐新峰%杨海东%张会轩%索延辉%沙中瑛
張明耀%徐新峰%楊海東%張會軒%索延輝%沙中瑛
장명요%서신봉%양해동%장회헌%색연휘%사중영
SAN树脂%增韧%小橡胶粒子%形态结构%力学性能
SAN樹脂%增韌%小橡膠粒子%形態結構%力學性能
SAN수지%증인%소상효입자%형태결구%역학성능
采用PB-g-SAN和SBR-g-SAN两种弹性体粒子分别与SAN树脂熔融共混,制得了一系列ABS树脂,研究了ABS树脂的形态结构和力学性能。结果发现,PB和SBR橡胶粒子均匀地分散在SAN基体中,其粒径分别为0.28μm和0.05μm左右。力学性能结果表明,在SAN树脂中随着PB-g-SAN含量的增加,ABS的冲击强度不断提高,而SBR小橡胶粒子不能增韧SAN树脂。但当SAN树脂中含有15%的PB-g-SAN共聚物时,随着SBR-g-SAN含量的增加,ABS树脂的冲击强度不断提高,SBR-g-SAN这种小橡胶粒子又表现出良好的增韧作用。
採用PB-g-SAN和SBR-g-SAN兩種彈性體粒子分彆與SAN樹脂鎔融共混,製得瞭一繫列ABS樹脂,研究瞭ABS樹脂的形態結構和力學性能。結果髮現,PB和SBR橡膠粒子均勻地分散在SAN基體中,其粒徑分彆為0.28μm和0.05μm左右。力學性能結果錶明,在SAN樹脂中隨著PB-g-SAN含量的增加,ABS的遲擊彊度不斷提高,而SBR小橡膠粒子不能增韌SAN樹脂。但噹SAN樹脂中含有15%的PB-g-SAN共聚物時,隨著SBR-g-SAN含量的增加,ABS樹脂的遲擊彊度不斷提高,SBR-g-SAN這種小橡膠粒子又錶現齣良好的增韌作用。
채용PB-g-SAN화SBR-g-SAN량충탄성체입자분별여SAN수지용융공혼,제득료일계렬ABS수지,연구료ABS수지적형태결구화역학성능。결과발현,PB화SBR상효입자균균지분산재SAN기체중,기립경분별위0.28μm화0.05μm좌우。역학성능결과표명,재SAN수지중수착PB-g-SAN함량적증가,ABS적충격강도불단제고,이SBR소상효입자불능증인SAN수지。단당SAN수지중함유15%적PB-g-SAN공취물시,수착SBR-g-SAN함량적증가,ABS수지적충격강도불단제고,SBR-g-SAN저충소상효입자우표현출량호적증인작용。
A series of ABS resins were prepared by melt blending PB-g-SAN and SBR-g-SAN elastomers with SAN resins respectively.The morphology and mechanical properties of ABS resins were studied.It was found that PB and SBR rubber particles were dispersed homogeneously in SAN matrix,and their particle sizes were about 0.28μm and 0.05μm respectively.The determination of mechanical properties showed that the impact strength of ABS resins increased gradually with increasing PB-g-SAN content in SAN matrix,and SAN resins could not be effectively toughened by SBR rubber particles.When PB-g-SAN content was 15% in ABS resins,the impact toughness of ABS resins was improved gradually with increasing SBR-g-SAN content in SAN resins.