CAJ | 학술논문

采用两种方法制备了三种Pt/CeO2-ZrO2-La2O3柴油车尾气氧化催化剂,并用X射线衍射、N2物理吸附、程序升温还原、程序升温脱附、X射线荧光光谱和红外光谱等方法对其进行了表征.结果发现,制备方法对催化剂的结构、织构、抗硫性能及催化性能的影响非常大.对其进行硫中毒,导致起燃温度明显升高.将ZrO2和La2O3沉积在CeO2表面所制得的Pt/CeO2-ZrO2-La2O3催化剂表现出更高的抗硫及催化氧化性能,这主要归功于Pt在富Zr载体表面具有更高的分散性.
채용량충방법제비료삼충Pt/CeO2-ZrO2-La2O3시유차미기양화최화제,병용X사선연사、N2물리흡부、정서승온환원、정서승온탈부、X사선형광광보화홍외광보등방법대기진행료표정.결과발현,제비방법대최화제적결구、직구、항류성능급최화성능적영향비상대.대기진행류중독,도치기연온도명현승고.장ZrO2화La2O3침적재CeO2표면소제득적Pt/CeO2-ZrO2-La2O3최화제표현출경고적항류급최화양화성능,저주요귀공우Pt재부Zr재체표면구유경고적분산성.
Three Pt/CeO2-ZrO2-La2O3 diesel oxidation catalysts were prepared by two different routes and characterized by X-ray diffraction,N2 adsorption,temperature-programmed reduction,temperature-programmed desorption,X-ray photoelectron spectroscopy,and infrared spectroscopy.The synthesis procedure affected the structure,texture,sulfur resistance,and catalytic activity of the catalysts.Sulfur poisoning increased the light-off temperature of all the catalysts,but the Pt/CeO2-ZrO2-La2O3 catalyst prepared by depositing ZrO2 and La2O3 on the surface of CeO2 nanoparticles exhibited better sulfur tolerance and catalytic activity with simulated diesel emission due to the high dispersion of Pt on CeO2-ZrO2-La2O3 oxide with a Zr-rieh surface.