中国化学工程学报(英文版)
中國化學工程學報(英文版)
중국화학공정학보(영문판)
CHINESE JOURNAL OF CHEMICAL ENGINEERING
2003年
6期
726-730
,共5页
林诚%朱涛%朱跃姿%张济宇
林誠%硃濤%硃躍姿%張濟宇
림성%주도%주약자%장제우
ultrafine CaCO3 particles%preparation%spouted bed%inert particles%reaction and drying%modeling
A novel reaction-drying process was carried out in a spouted bed reactor with inert particles and used to prepare ultrafine CaCO3 particles. Effects of concentrations of CO2 and Ca(OH)2, and reaction temperature on Ca(OH)2 conversion were experimentally investigated. The particle sizes and composition of CaCO3 produced were characterized with transmission electron microscopy (TEM) and X-ray diffraction (XRD). The results indicated that ultrafine CaCO3 particles with mean size of 80 nm could be obtained with this novel process.By modifying the Arrhenius Equation and considering the Ca(OH)2 state, a kinetic model was established to describe the process in the spouted bed. The model parameters estimated from the reaction-drying experiments were found to fit well the experimental data, indicating the applicability of the proposed kinetic model.
