中国有色金属学会会刊(英文版)
中國有色金屬學會會刊(英文版)
중국유색금속학회회간(영문판)
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
2003年
2期
448-451
,共4页
李新军%李芳柏%古国榜%柳松%王良焱%梁园园
李新軍%李芳柏%古國榜%柳鬆%王良焱%樑園園
리신군%리방백%고국방%류송%왕량염%량완완
adsorption%methyl orange%TiO2%surface complexation%photocatalysis
Based on the infrared characterization of methyl orange adsorption on TiO2 surface and the titration of TiO2, the triple layer model of methyl orange adsorption on TiO2 was established according to electric double theory. The software FITEQL3.1 was applied to calculate the distribution of organic adsorption on TiO2 surface by introducing dummy components to help to overcome mathematical difficulties. It is shown that the chem. -adsorption species of methyl orange have a great adsorption amount. The adsorption constants of three kinds of surface complexation expressed as SOH+org-,SOH2org2 and SOHorg- are 5.98, 17.57 and -4.2, respectively.
