化学试剂
化學試劑
화학시제
CHEMICAL REAGENTS
2009年
12期
1018-1020
,共3页
刘冬梅%盛继文%王思宏%李耀辉
劉鼕梅%盛繼文%王思宏%李耀輝
류동매%성계문%왕사굉%리요휘
(R)/(S)-2-苄基丁二酸1-叔丁酯%(R)/(S)-2-异丁基丁二酸1-叔丁酯%化学拆分%α-苯乙胺
(R)/(S)-2-芐基丁二痠1-叔丁酯%(R)/(S)-2-異丁基丁二痠1-叔丁酯%化學拆分%α-苯乙胺
(R)/(S)-2-변기정이산1-숙정지%(R)/(S)-2-이정기정이산1-숙정지%화학탁분%α-분을알
1-tert-butyl ester of (R)/(S)-2-benzylsuccinic acid%1-tert-butyl ester of (R)/(S)-2-isobutylsuccinic acid%chemical resolution%α-methylbenzylamine
在乙酸乙酯中,对2-取代丁二酸1-叔丁酯和手性α-苯乙胺形成的非对映体盐进行化学拆分,得到了(R)-和(S)-2-取代丁二酸1-叔丁酯.
在乙痠乙酯中,對2-取代丁二痠1-叔丁酯和手性α-苯乙胺形成的非對映體鹽進行化學拆分,得到瞭(R)-和(S)-2-取代丁二痠1-叔丁酯.
재을산을지중,대2-취대정이산1-숙정지화수성α-분을알형성적비대영체염진행화학탁분,득도료(R)-화(S)-2-취대정이산1-숙정지.
The (R)- and (S)-2-substituted 1-tert-butyl succinates were obtained by formation of their salts with chiral (R)- or (S)-α-methylbenzylamine in ethyl acetate,respectively.
