CAJ | 학술논문

在HCl介质中,Bi(Ⅲ)与I~- 可形成[BiI4]- 络合负离子,与质子化的诺氟沙星(NRF)缔合,形成离子缔合物,使共振瑞利散射(RRS)显著增强,并且最大RRS峰位于469 nm处.在优化的实验条件下,RRS强度增大值(ΔI)与NRF浓度成正比,线性范围和检出限分别为3.2～130 μg/L和 0.96 μg/L,方法简单,灵敏度高,用于牛奶样品中NRF测定,结果满意.
재HCl개질중,Bi(Ⅲ)여I~- 가형성[BiI4]- 락합부리자,여질자화적낙불사성(NRF)체합,형성리자체합물,사공진서리산사(RRS)현저증강,병차최대RRS봉위우469 nm처.재우화적실험조건하,RRS강도증대치(ΔI)여NRF농도성정비,선성범위화검출한분별위3.2～130 μg/L화 0.96 μg/L,방법간단,령민도고,용우우내양품중NRF측정,결과만의.
In HCl media,Bi(Ⅲ) was reacted with I~- to form ion complex[BiI4]-,which further associate with norfloxacin (NRF) to form the association complex,resulting in the new resonance Rayleigh scattering(RRS) is significantly enhanced and the maximum RRS wavelength is located at 469 nm.Under the optimum condition,the linear ranges and the detection limits are 3.2～130 μg/L and 0.96 μg/L,respectively.This method is simple,sensitive.The NRF in milk samples were analyzed by the proposed method with satisfactory results.