CAJ | 학술논문

以牡蛎壳和废玻璃粉为主要原料制备了空心管状型体废水除磷材料,探讨了在500～650℃不同预烧温度、不同样品配方及与废水接触不同时间下样品的废水除磷效果,从而选择最佳制备条件.采用XRD及SEM表征样品的微观结构及组成,采用磷钼蓝分光光度法测定废水中磷的含量.结果表明,含废玻璃粉20%、牡蛎壳80%的样品在600℃煅烧时除磷效果最好,12天后除磷率达到99%;XRD分析显示此时样品主要由3种晶相组成,CaCO3、SiO2和CaO,说明在此温度下牡蛎壳中的部分CaCO3已经分解为CaO.
이모려각화폐파리분위주요원료제비료공심관상형체폐수제린재료,탐토료재500～650℃불동예소온도、불동양품배방급여폐수접촉불동시간하양품적폐수제린효과,종이선택최가제비조건.채용XRD급SEM표정양품적미관결구급조성,채용린목람분광광도법측정폐수중린적함량.결과표명,함폐파리분20%、모려각80%적양품재600℃단소시제린효과최호,12천후제린솔체도99%;XRD분석현시차시양품주요유3충정상조성,CaCO3、SiO2화CaO,설명재차온도하모려각중적부분CaCO3이경분해위CaO.
Hollow cylindric materials for removing phosphate from waste water is prepared in this research.The influences of different calcining temperatures from 500℃ to 650℃ ,different prescription and different contact time on phosphate removal effects are discussed. XRD and SEM techniques are used to investigate the crystals and microstructures. Ammonium phosphomolybdate spectrophotometry method is used to detect the concentration of phosphorous in wastewater. Results show that No. 2 sample with 20% of waste glass powder and 80% of oyster shell powder have the best phosphate remove effect,which can remove 99% of phosphate after contact with waste water for 12 days.XRD shows that 3 crystal phases exist,CaCO3 ,SiO2 and CaO, which suggests that certain amount of CaCO3 decomposed into CaO at this temperature.