CAJ | 학술논문

延迟焦化工艺生产过程中有时会产生弹丸焦,通过对渣油生焦机理和形成弹丸焦时的渣油性质进行分析,得出渣油的沥青质含量、金属(V+Ni)含量高是产生弹丸焦的原因.采取渣油合理掺炼,控制渣油中的沥青质含量不大于9.3%、稳定因子不大于0.30、金属(V+Ni)含量不大于244 μg/g,可以避免弹丸焦产生,另外通过降低加热炉温度、提高循环比和反应压力等优化操作手段,也可以抑制弹丸焦的生成.
연지초화공예생산과정중유시회산생탄환초,통과대사유생초궤리화형성탄환초시적사유성질진행분석,득출사유적력청질함량、금속(V+Ni)함량고시산생탄환초적원인.채취사유합리참련,공제사유중적력청질함량불대우9.3%、은정인자불대우0.30、금속(V+Ni)함량불대우244 μg/g,가이피면탄환초산생,령외통과강저가열로온도、제고순배비화반응압력등우화조작수단,야가이억제탄환초적생성.
Shot coke was formed in delayed coking unit when processing poor quality crude oils.By reviewing coke formation mechanism and analyzing the properties of residue feedstock which shot coke was formed,it was found that high in asphaltene and metals(Ni+V)contents of feedstock was the main cause of shot coke formation.Measures,such as proper adjusting the blending ratios of various residue feeds to control the feedstock properties including asphaltene content,metals content and stable factor not more than 9.3%,244μg/g and 0.30,respectively,could significantly reduce the chance of forming shot coke.Furthermore,when processing poor quality residue feedstock,optimizing operation parameters,such as decreasing furnace outlet temperature,increasing recycle ratio and reaction pressure,could suppress the formation of shot coke as well.