CAJ | 학술논문

通过固相合成的方法制备了Bi3.25LaxTi3O12(x=0.98～1.03,简称BLT)陶瓷.通过XRD,SEM和阻抗分析仪表征了陶瓷的晶体结构和晶体形貌,测试了陶瓷的介电频谱,结果表明陶瓷的晶体结构为典型的层状钙钛矿结构且不随Bi含量和温度的变化而改变;随着Bi含量的增加晶体形貌由棒状颗粒向片状颗粒转变,而且陶瓷的致密度也得到提高;介电常数随Bi含量的增加先增大后减小,并且在x=1.02时达到最大值.
통과고상합성적방법제비료Bi3.25LaxTi3O12(x=0.98～1.03,간칭BLT)도자.통과XRD,SEM화조항분석의표정료도자적정체결구화정체형모,측시료도자적개전빈보,결과표명도자적정체결구위전형적층상개태광결구차불수Bi함량화온도적변화이개변;수착Bi함량적증가정체형모유봉상과립향편상과립전변,이차도자적치밀도야득도제고;개전상수수Bi함량적증가선증대후감소,병차재x=1.02시체도최대치.
Lanthanum-modified bismuth titanate, Bi3.25-x La0.75Ti3O12 (BLT) ceramics, with x ranging from 0.98 to 1.03 were prepared by the conventional solid-solution technique. The crystal structure, morphological and dielectric properties of BLT ceramics were investigated by the X-ray diffraction (XRD), the scanning electron microscopy (SEM) and the impendence analyzer. It is indicated that the crystal structure of ceramic is a classic Bi-layer perovskite structure. The crystal structure doesn't change with bismuth content and the sintering temperature. The micro morphology transformes from stick-like crystal grains to slice-like crystal grains with bismuth content increasing . The dielectric constant firrstly increases then decreases with increasing content of bismuth, and arrives at a maximum at x = 1.02.