CAJ | 학술논문

在合成和表征不同类型的聚苯硫醚树脂的基础上，对不同类型PPS的流变行为以及各类PPS的结晶度及热历程对不同结构类型PPS的结晶度的影响进行了研究，结果表明，各种聚苯硫醚树脂在相同条件下的流变性能有所不同，各种聚苯硫醚树脂的结晶度，及热历程对其结晶行为的影响也有差异
재합성화표정불동류형적취분류미수지적기출상，대불동류형PPS적류변행위이급각류PPS적결정도급열역정대불동결구류형PPS적결정도적영향진행료연구，결과표명，각충취분류미수지재상동조건하적류변성능유소불동，각충취분류미수지적결정도，급열역정대기결정행위적영향야유차이
The rheological property and crystalline properties of different types of poly (phenylene Sulfide) s have been studied with rheometer and DSC. The results show that the linear PPS is not pseudoplastic fluid but expanion fluid, the high molecular PPS and modified high molecular PPS are pseudoplastic fluids and the modified high molecular PPSs tend to flow more Newtonian than do other type PPS, the commonly used PPS flows too fast to obtain the rheology data, and the branched PPS and the oxygen cured/crossed PPS are so viscous that they can not pass the rheometer. In the terms of thermal and crystalline properties, all types of PPSs have different melting point and the crystallinity, the quenching(melt at 300Cand quenched in water) and the heating in the air at 310C for 30 minutes have more effects on the commonly used PPS and the branched PPS than on the high molecular PPS and modified high molecular PPS, The crystallinity of the commonly used PPS rises slightly, the crystallinity of the modified high molecular PPS almost has no changes, and the branched PPS become the amorphous.