结构化学
結構化學
결구화학
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
2000年
1期
15-18
,共4页
张玉华%吴树林%李庆山%宋翠萍%殷元琪%黄小荥
張玉華%吳樹林%李慶山%宋翠萍%慇元琪%黃小滎
장옥화%오수림%리경산%송취평%은원기%황소형
synthesis%crystal structure%tetrahedral framework%heterometallic cluster
The chiral sulfido cluster (η5-EtO(O)CC5H4)RuCoMo(μ3-S)(CO)8 was synthesized by refluxing a solution of SRuCo2 (CO)9 and Na[Mo(CO)3CpC(O) OEt] in tetrahydrofuran. It was characterized by elemental analysis, IR and 1H-NMR.Crystal data: C 16H9O)10CoMoRuS, Mr=649.24, monoclinic, space group P21/n, a =10.075(1), b = 9.034(2), c = 22.973(7) A, β= 92.70(1), V = 2088.7(8)A3,296K, final R = 0. 030, Rw= 0. 042 for 3686 observed reflections with I＞2. 00σ(I).The crystal structure determination shows that the cluster has a chiral tetrahedral core containing a ethoxycarbonyl attached to the cyclopentadienyl.
