CAJ | 학술논문

利用共沉淀水热法制备镁铝阴离子黏土材料,研究了其水溶液对砷酸根[As(V)]离子的吸附热力学及其机理.结果表明:在303～333 K和试验浓度范围内,阴离子黏土对水中As(V)的吸附平衡数据符合Langmuir 和Freundlich吸附等温方程.阴离子黏土对水中As(V)的吸附是吸热过程;根据热力学函数关系计算出As(V)在阴离子黏土上的吸附焓为2.85 kJ/mol,吉布斯吸附自由能改变量为-6.64～-5.90 kJ/mol,吸附自由能的变小是As(V)在阴离子黏土上吸附的推动力,吸附熵变为29.38 J/(mol·K).
이용공침정수열법제비미려음리자점토재료,연구료기수용액대신산근[As(V)]리자적흡부열역학급기궤리.결과표명:재303～333 K화시험농도범위내,음리자점토대수중As(V)적흡부평형수거부합Langmuir 화Freundlich흡부등온방정.음리자점토대수중As(V)적흡부시흡열과정;근거열역학함수관계계산출As(V)재음리자점토상적흡부함위2.85 kJ/mol,길포사흡부자유능개변량위-6.64～-5.90 kJ/mol,흡부자유능적변소시As(V)재음리자점토상흡부적추동력,흡부적변위29.38 J/(mol·K).
Mg-Al anionic clay materials were prepared by co-precipitation hydrothermal method and the adsorption thermodynamic and mechanism of arsenate anion from its aqueous solutions were investigated.Equilibrium data for the adsorption of arsenate anion from aqueous solutions within the temperature rang of 303-333 K and investigative concentration rang was obtained and correlated with a Langmuir-type and Freundlich-type isotherm equations.The results showed that the process of sorption of arsenate anion from aqueous solutions by Mg-Al anionic clay was an endothermic process.The adsorption parameters of thermodynamic were calculated according to the relationship of thermodynamic function,enthalpy was 2.85 KJ/mol,adsorption free energy was in the range of -6.64--5.90 kJ/mol,the adsorption happened because of the decrease of Gibbs free energy and adsorption entropy was 29.38 J/(mol ·K).