南开大学学报（自然科学版）
南開大學學報（自然科學版）
남개대학학보（자연과학판）
ACTA SCIENTIARUM NATURALIUM UNIVERSITATIS NANKAIENSIS(NATURAL SCIENCE EDITION)
2004年
4期
10-13
,共4页
田金磊%许光军%阎世平%廖代正%姜宗慧%程鹏
田金磊%許光軍%閻世平%廖代正%薑宗慧%程鵬
전금뢰%허광군%염세평%료대정%강종혜%정붕
晶体结构%锰配合物%2D氢键网络%水热合成
晶體結構%錳配閤物%2D氫鍵網絡%水熱閤成
정체결구%맹배합물%2D경건망락%수열합성
crystal structures%manganess ( Ⅱ ) complex%2D network structure%hydrogen bonds%hydrothermal synthesis
利用水热合成方法,得到了一个新型的锰配合物[Mn(BBP-H)2](BBP为2,6-双(2-苯并咪唑甲基)吡啶),并通过X-射线衍射得到其晶体结构,空间群为P-4n2,晶胞参数a=1.01 470(17)nm,b=1.014 70(17)nm,c=1.588 5(5)nm,V=1.635 5(7)nm3,Z=2.每个锰离子与两个带电荷的三齿配体BBP配位,形成畸变的八面体构型,相邻的分子之间通过氢键形成2D平面结构.
利用水熱閤成方法,得到瞭一箇新型的錳配閤物[Mn(BBP-H)2](BBP為2,6-雙(2-苯併咪唑甲基)吡啶),併通過X-射線衍射得到其晶體結構,空間群為P-4n2,晶胞參數a=1.01 470(17)nm,b=1.014 70(17)nm,c=1.588 5(5)nm,V=1.635 5(7)nm3,Z=2.每箇錳離子與兩箇帶電荷的三齒配體BBP配位,形成畸變的八麵體構型,相鄰的分子之間通過氫鍵形成2D平麵結構.
이용수열합성방법,득도료일개신형적맹배합물[Mn(BBP-H)2](BBP위2,6-쌍(2-분병미서갑기)필정),병통과X-사선연사득도기정체결구,공간군위P-4n2,정포삼수a=1.01 470(17)nm,b=1.014 70(17)nm,c=1.588 5(5)nm,V=1.635 5(7)nm3,Z=2.매개맹리자여량개대전하적삼치배체BBP배위,형성기변적팔면체구형,상린적분자지간통과경건형성2D평면결구.
One two-dimensional H-bonded network complex: [Mn (BBP-H)2 ] (BBP = 2,6-bis (benzimidazol2-yl)pyridine) has been synthesized from hydrothermal solutions at 150 ℃. It crystallizes in Tetragonal system,space group P-4n2 with a=1. 014 70(17) nm, b=1. 01 470(17) nm, c=1. 588 5(5) nm, V=1. 635 5(7) nm3,Z = 2. Crystal analyses reveal that the manganese atom is coordinated by two charged BBP ligand, thus generating a distorted-octahedron geometry. A notable feature of the complex is that each complex is connected with four surrounding ones to form 2D network by hydrogen bonds.
