无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2006年
7期
1345-1348
,共4页
诸海滨%沈宏%李根喜%苟少华
諸海濱%瀋宏%李根喜%茍少華
제해빈%침굉%리근희%구소화
双核铜(Ⅱ)%大环席夫碱%1,4-二胺%不对称催化
雙覈銅(Ⅱ)%大環席伕堿%1,4-二胺%不對稱催化
쌍핵동(Ⅱ)%대배석부감%1,4-이알%불대칭최화
dinuclear copper(Ⅱ)%macrocyclic Schiff base%1,4-diamines%asymmetric catalysis
Dinuclear copper(Ⅱ) complexes of [2+2] macrocyclic Schiff bases have been prepared from chiral 1,4-diamines using sodium ions as template. Catalytic investigation on the titled complexes has been carried out on model reactions (asymmetric sulfoxidation and asymmetric oxidative-coupling reactions).