CAJ | 학술논문

在十二烷基磺酸钠（SLS）存在条件下,基于KI和Hg（Ⅱ）形成[HgI4]2-络阴离子后与四丙基溴化铵（TPAB）结合形成离子缔合物使共振光散射（RLS）信号强度明显增强,建立了运用共振光散射技术测定水样中汞含量的新方法。研究了四丙基溴化铵-碘化钾-汞体系的共振光谱特征,在393nm处体系的散射光强度最大.在最佳实验条件下,体系的共振光散射强度与Hg（II）浓度在0.05～1.0μg.mL-1范围内呈良好的线性关系。用此方法测定合成水样中的Hg（II）,操作简便快速,回收率在96.17%～101.67%之间,结果令人满意.
재십이완기광산납（SLS）존재조건하,기우KI화Hg（Ⅱ）형성[HgI4]2-락음리자후여사병기추화안（TPAB）결합형성리자체합물사공진광산사（RLS）신호강도명현증강,건립료운용공진광산사기술측정수양중홍함량적신방법。연구료사병기추화안-전화갑-홍체계적공진광보특정,재393nm처체계적산사광강도최대.재최가실험조건하,체계적공진광산사강도여Hg（II）농도재0.05～1.0μg.mL-1범위내정량호적선성관계。용차방법측정합성수양중적Hg（II）,조작간편쾌속,회수솔재96.17%～101.67%지간,결과령인만의.
A new method has been developed for the determination of Mercury based on the enhanced resonance light scattering（RLS）intensity resulting from the complex formed by 2-and tet rapropyl ammonium bromide（TPAB） in the presence of sodium dodecyl sulphate（SLS）.The characteristics of RLS spectra of ion-association complex have been investigated and the maximum RLS peaks at 393 nm.Under the optimum condition,there is a good linear relationship between the RLS and the concent ration of Mercury in the range of 0.05~1.0μg/ mL.This method is simple and speedy.It is successfully applied to determine Mercury in synthesized sample and the results are satisfactory,with the recovery between 96.17%~101.67%.