中国化学工程学报(英文版)
中國化學工程學報(英文版)
중국화학공정학보(영문판)
CHINESE JOURNAL OF CHEMICAL ENGINEERING
2008年
4期
547-551
,共5页
张晓冬%付勇%李志义%赵宗昌
張曉鼕%付勇%李誌義%趙宗昌
장효동%부용%리지의%조종창
hydrodynamic cavitation%collapse pressure%numerical simulation%free hydroxyl radical
Enhancing the chemical reaction processes by means of the energy released in the collapse of micro bubbles or cavities in the cavitation flow is a new research area.In the previous work,a new approach of measuring concentration of free hydroxyl radicals induced in cavitation flow by using methylene blue as the indicator was developed and used to study concentration of free radical induced in Venturi cavitation flow under various experimental conditions.In the present research.the radjal evolution of a cavity bubble and the corresponding collapse pressure in sonic cavitation field are obtained by solving three different bubble dynamics equations:Rayleigh equation.Rayleigh-Plesset equation and Gilmore equation.By comparing with the experimental daIa on the radial evolution of a cavity bubble in the literature,it is found that the predicted results bv the Gilmore equation,Which takes account of the compressibility of fluid in addition to the viscosity and interfacial tension.agree with the experimental ones better than those by other two equatlons.Moreover,the theoretically predicted collapse pressures are consistent with the concentration of the free hydroxyl radical induced in the experimental venture,Thus.the concentration of the liberated free hydroxyl radical not only influences the reaction rate but also is used as an available parameter for measuring collapse intensity of cavities.