无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2009年
6期
1137-1140
,共4页
2-吡嗪羧酸%铜%晶体结构%配位聚合物
2-吡嗪羧痠%銅%晶體結構%配位聚閤物
2-필진최산%동%정체결구%배위취합물
2-pyrazinic acid%copper%,crystal structure%coordination polymer
Solvothermal reaction of 2-pyrazinic acid with Cu(SO4) 2·5H2O yields the title complex {[Cu2 (Pyz) 2 (H2O) 4]·SO4}n (1), which was characterized by elemental analysis, IR and single crystal X-ray diffraction structural analysis. The complex 1 crystallizes in Monoclinic system, space group P21/c, with lattice parameters a=1.126 87(6)nm, b=0.073 511 (4) nm,c=1.185 06(7) nm,β=95.070(2)°,and V=0.977 83(9) nm3,Z=4,Dc=2.172 Mg·m-3. CCDC:692347.
