纳米技术与精密工程
納米技術與精密工程
납미기술여정밀공정
NANOTECHNOLOGY AND PRECISION ENGINEERING
2009年
6期
515-518
,共4页
赵瑜%江洵%李成垚%王玮%高旻%李志宏
趙瑜%江洵%李成垚%王瑋%高旻%李誌宏
조유%강순%리성요%왕위%고민%리지굉
纳米颗粒单层膜%纳米针尖阵列%反应离子刻蚀%场发射效应
納米顆粒單層膜%納米針尖陣列%反應離子刻蝕%場髮射效應
납미과립단층막%납미침첨진렬%반응리자각식%장발사효응
nanoparticle monolayer%nanopillar array%reactive ion etching(RIE)%field emission effect
系统地研究了硅衬底上二氧化硅纳米颗粒的反应离子刻蚀(RIE)过程,并在此基础上制备了可用于场发射的硅纳米针尖阵列.首先,采用改进的蒸发法在硅衬底上实现二氧化硅纳米颗粒的单层密排结构,再采用典型的刻蚀二氧化硅的RIE技术同时刻蚀硅衬底和二氧化硅纳米颗粒,在对纳米颗粒尺寸随刻蚀进行而改变的电镜照片分析的基础上,获得了相应的二氧化硅纳米颗粒刻蚀模型,计算得到横向和纵向的刻蚀速率;当刻蚀后的二氧化硅纳米颗粒从衬底上脱落后,进一步对硅衬底的刻蚀可以得到锐利的硅纳米针尖阵列,初步的实验结果表明,所制备的硅纳米针尖具有较好的场发射特性.
繫統地研究瞭硅襯底上二氧化硅納米顆粒的反應離子刻蝕(RIE)過程,併在此基礎上製備瞭可用于場髮射的硅納米針尖陣列.首先,採用改進的蒸髮法在硅襯底上實現二氧化硅納米顆粒的單層密排結構,再採用典型的刻蝕二氧化硅的RIE技術同時刻蝕硅襯底和二氧化硅納米顆粒,在對納米顆粒呎吋隨刻蝕進行而改變的電鏡照片分析的基礎上,穫得瞭相應的二氧化硅納米顆粒刻蝕模型,計算得到橫嚮和縱嚮的刻蝕速率;噹刻蝕後的二氧化硅納米顆粒從襯底上脫落後,進一步對硅襯底的刻蝕可以得到銳利的硅納米針尖陣列,初步的實驗結果錶明,所製備的硅納米針尖具有較好的場髮射特性.
계통지연구료규츤저상이양화규납미과립적반응리자각식(RIE)과정,병재차기출상제비료가용우장발사적규납미침첨진렬.수선,채용개진적증발법재규츤저상실현이양화규납미과립적단층밀배결구,재채용전형적각식이양화규적RIE기술동시각식규츤저화이양화규납미과립,재대납미과립척촌수각식진행이개변적전경조편분석적기출상,획득료상응적이양화규납미과립각식모형,계산득도횡향화종향적각식속솔;당각식후적이양화규납미과립종츤저상탈락후,진일보대규츤저적각식가이득도예리적규납미침첨진렬,초보적실험결과표명,소제비적규납미침첨구유교호적장발사특성.
Reactive ion etching (RIE) of SiO_2 nanoparticles on a silicon substrate has been systemically studied in this paper and a silicon nanopillar array has been prepared with this technique for field emission. A monolayer of SiO_2 nanoparticles was first obtained on a Si wafer by the revised evaporation approach. Then the Si wafer and the SiO_2 nanoparticles were etched by RIE anisotropically with a typical silicon oxide etching recipe. On the basis of analysis of the geometrical data of the shrunk nanoparticles in SEM images, the RIE process of the SiO_2 nanoparticles was modeled, and the horizontal and vertical etching rates were calculated based on the proposed geometrical model. Besides, a further etching of the silicon substrate after the nanoparticles brushed off led to a sharp silicon nanopillar array. Preliminary experiment result indicates that the so-prepared silicon nanopillar has good performance in field emission.