石油与天然气化工
石油與天然氣化工
석유여천연기화공
CHEMICAL ENGINEERING OF OIL AND GAS
2009年
5期
426-429,433
,共5页
田发国%李建波%颜紫霖%殷留义%全红平
田髮國%李建波%顏紫霖%慇留義%全紅平
전발국%리건파%안자림%은류의%전홍평
曼尼希反应%酸化缓蚀剂%性能评价
曼尼希反應%痠化緩蝕劑%性能評價
만니희반응%산화완식제%성능평개
Mannich reaction%aciding corrosion inhibitor%performance evaluation
油井酸化作业是油田增产的主要措施.随着深井和超深井的不断出现,对于这些油井的复杂酸化作业,许多缓蚀剂表现出酸溶性不佳,抗温能力差,缓蚀性能不好等问题.如果通过增加缓蚀剂的用量来提高缓蚀剂对井下金属设备和管线的防护能力,不仅会增加酸化作业的成本,对酸化作业带来不利影响,而且有可能对地层造成伤害.所以,开发良好性能的缓蚀剂具有重要现实意义.本试验以甲醛、苯乙酮、乙二胺为主要原料,通过曼尼希反应所得产品与氯化苄反应,得到了一种油井抗高温的酸化缓蚀剂SYB,并对缓蚀剂SYB的酸溶性、缓蚀性等性能进行了评价.评价结果表明:该缓蚀剂的酸溶性较好,与其他酸化添加剂配伍性好,无毒,能抗高温,在不同酸液中均表现出了优良的缓蚀性能.
油井痠化作業是油田增產的主要措施.隨著深井和超深井的不斷齣現,對于這些油井的複雜痠化作業,許多緩蝕劑錶現齣痠溶性不佳,抗溫能力差,緩蝕性能不好等問題.如果通過增加緩蝕劑的用量來提高緩蝕劑對井下金屬設備和管線的防護能力,不僅會增加痠化作業的成本,對痠化作業帶來不利影響,而且有可能對地層造成傷害.所以,開髮良好性能的緩蝕劑具有重要現實意義.本試驗以甲醛、苯乙酮、乙二胺為主要原料,通過曼尼希反應所得產品與氯化芐反應,得到瞭一種油井抗高溫的痠化緩蝕劑SYB,併對緩蝕劑SYB的痠溶性、緩蝕性等性能進行瞭評價.評價結果錶明:該緩蝕劑的痠溶性較好,與其他痠化添加劑配伍性好,無毒,能抗高溫,在不同痠液中均錶現齣瞭優良的緩蝕性能.
유정산화작업시유전증산적주요조시.수착심정화초심정적불단출현,대우저사유정적복잡산화작업,허다완식제표현출산용성불가,항온능력차,완식성능불호등문제.여과통과증가완식제적용량래제고완식제대정하금속설비화관선적방호능력,불부회증가산화작업적성본,대산화작업대래불리영향,이차유가능대지층조성상해.소이,개발량호성능적완식제구유중요현실의의.본시험이갑철、분을동、을이알위주요원료,통과만니희반응소득산품여록화변반응,득도료일충유정항고온적산화완식제SYB,병대완식제SYB적산용성、완식성등성능진행료평개.평개결과표명:해완식제적산용성교호,여기타산화첨가제배오성호,무독,능항고온,재불동산액중균표현출료우량적완식성능.
In oil wells development,the acidification is the important stimulation treatments. With deep wells and over deep wells exploited,lots of corrosion inhibitors show some problems.For example, poor dissolution and bad anticorrosion properties, etc... If the underground metal equipment and pipeline were protected by increasing the amount of corrosion inhibitor, this would not only increase the cost and lead to an adverse impact on operations, but also have a possibility of formation damage. Therefore, the development of corrosion inhibitors with the good performance is very important and practical significance. In this paper, formaldehyde, acetophenone, ethylene diamine were used to be the main raw materials through Mannich reaction to get a condensation compound, and then it was reacted with benzyl chloride to get a high temperature aciding corrosion inhibitor SYB.Meanwhile, acid-soluble, inhibition of corrosion and others performance of SYB were evaluated. The results show that the acid-soluble corrosion inhibitor is nonpoisonous,compatibility with other additives,resistant to high temperature, in different acid it was shown excellent corrosion properties.