暨南大学学报（自然科学与医学版）
暨南大學學報（自然科學與醫學版）
기남대학학보（자연과학여의학판）
JOURNAL OF JINAN UNIVERSITY（NATURAL SCIENCE & MEDICINE EDITION）
2009年
5期
534-538
,共5页
刘任富%梁冠科%陈茵%谭绍早%谢瑜珊%欧阳友生%施庆珊
劉任富%樑冠科%陳茵%譚紹早%謝瑜珊%歐暘友生%施慶珊
류임부%량관과%진인%담소조%사유산%구양우생%시경산
季鳞盐%柱撑蒙脱土%制备%表征%抗菌活性
季鱗鹽%柱撐矇脫土%製備%錶徵%抗菌活性
계린염%주탱몽탈토%제비%표정%항균활성
quaternary phosphonium salt%pillared montmorillonites%preparation%characteriza-tion%antimicrobial activity
采用离子交换法将不同组份的十烷基三丁基溴化鳞交换到蒙脱土的层间得到柱撑蒙脱土.用热重分析(TGA)、X-射线衍射(XRD)和傅里叶变换红外光谱法(FTIR)等对其结构进行了表征,并测定其抗菌活性.研究发现柱撑蒙脱土中季鳞盐的热分解起始温度大于210℃,具有较好的热稳定性;季鳞盐含量越高,柱撑蒙脱土的层间距越大,抗菌活性越高.
採用離子交換法將不同組份的十烷基三丁基溴化鱗交換到矇脫土的層間得到柱撐矇脫土.用熱重分析(TGA)、X-射線衍射(XRD)和傅裏葉變換紅外光譜法(FTIR)等對其結構進行瞭錶徵,併測定其抗菌活性.研究髮現柱撐矇脫土中季鱗鹽的熱分解起始溫度大于210℃,具有較好的熱穩定性;季鱗鹽含量越高,柱撐矇脫土的層間距越大,抗菌活性越高.
채용리자교환법장불동조빈적십완기삼정기추화린교환도몽탈토적층간득도주탱몽탈토.용열중분석(TGA)、X-사선연사(XRD)화부리협변환홍외광보법(FTIR)등대기결구진행료표정,병측정기항균활성.연구발현주탱몽탈토중계린염적열분해기시온도대우210℃,구유교호적열은정성;계린염함량월고,주탱몽탈토적층간거월대,항균활성월고.
Pillared montmorillonites were prepared by introducing different content of deeyltribu-tylphosphonium bromide into sodium montmorillonite through ion-exchange method. The structures were studied by thermogravimetric analysis (TGA) methods, X-ray diffraction (XRD) technique and fourier transform infrared (FrIR) spectroscopy. Also the antirnicrobial activity was studiesd. The results showed that the onset temperatrure of the decomposition for quaternary phosphonium salts in pillared montmoril-lonites were all higher than 210℃, and they were preferable thermal stability. The interlayer spacings ofmontmorilonites enlarged and the antimicrobial activity improved with the increase of the content of qua-ternary phosphonium salts in pillared montmorillonites.
