贵金属
貴金屬
귀금속
PRECIOUS METALS
2010年
1期
37-42,47
,共7页
有机化学%太阳能电池%金属有机配合物%光敏剂
有機化學%太暘能電池%金屬有機配閤物%光敏劑
유궤화학%태양능전지%금속유궤배합물%광민제
organic chemistry%solar cell%metal organic complex%photosensitizer
在染料敏化太阳能电池(DSSC)中,染料敏化剂用以吸收光子,具有较宽光谱吸收范围,它直接决定了电池的能量转换效率,因而近年来得到飞速发展,成果显著.论文以钌基多吡啶配合物染料为主,综述了包括卟啉、酞菁及纯有机染料在内的多种光敏剂的设计合成路线、特点及其对染料敏化太阳能电池性能的影响,并展望了今后染料敏化剂的研究与开发思路.
在染料敏化太暘能電池(DSSC)中,染料敏化劑用以吸收光子,具有較寬光譜吸收範圍,它直接決定瞭電池的能量轉換效率,因而近年來得到飛速髮展,成果顯著.論文以釕基多吡啶配閤物染料為主,綜述瞭包括卟啉、酞菁及純有機染料在內的多種光敏劑的設計閤成路線、特點及其對染料敏化太暘能電池性能的影響,併展望瞭今後染料敏化劑的研究與開髮思路.
재염료민화태양능전지(DSSC)중,염료민화제용이흡수광자,구유교관광보흡수범위,타직접결정료전지적능량전환효솔,인이근년래득도비속발전,성과현저.논문이조기다필정배합물염료위주,종술료포괄계람、태정급순유궤염료재내적다충광민제적설계합성로선、특점급기대염료민화태양능전지성능적영향,병전망료금후염료민화제적연구여개발사로.
The dye-sensitizers of dye sensitized solar cell (DSSC) enjoy wide spectral absorption band, which has decisive effect on the photoelectric conversion efficiency (η). In recent years, the sensitizers have been investigated widely and rapid development has been achieved. In this paper, the design and synthesis of different dyes (porphyrin, phthalocyanine and the pure organic dyes, especially the ruthenium polypyridyl complexes), their properties and effects on the DSSC are reviewed, and future development is also introduced.