中国稀土学报(英文版)
中國稀土學報(英文版)
중국희토학보(영문판)
JOURNAL OF RARE EARTHS
2001年
4期
250-254
,共5页
于桂红%乐善堂%李德谦%凤优游
于桂紅%樂善堂%李德謙%鳳優遊
우계홍%악선당%리덕겸%봉우유
Ce4+ extraction rate from aqueous sulphate solutions by Cyanex923 in heptane was studied using a constant interfacial cell with laminar flow at 30 ℃. The experimental hydrodynamic conditions were chosen and the contribution of diffusion to the measured rate of reaction was minimized. Cerium extraction rate was measured at different chemical composition by varying the concentrations of hydrogen ion, sulphate and Cyanex923. A cerium-Cyanex923(B) extractive is formed at the interface. The data were analyszed in terms of pseudo-first order constants and a reaction mechanism was developed.
