N,N'-苄基-1,2二胺合铜的合成和晶体结构及与DNA的相互作用
N,N'-변기-1,2이알합동적합성화정체결구급여DNA적상호작용
Synthesis, Crystal Structure and Interaction with DNA of (N,N'-dibenzylethane-1,2-diamine) Copper(Ⅱ)
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2007年 12期 2119-2122 ,共4页

    吴姗姗%袁文兵%张岐%顾海波%郁开北

    오산산%원문병%장기%고해파%욱개북

    金属配合物%晶体结构%合成%小牛胸腺DNA 金屬配閤物%晶體結構%閤成%小牛胸腺DNA
    금속배합물%정체결구%합성%소우흉선DNA
    metal complex%crystal structure%synthesis%calf thymus DNA


    A ligand, (N,N'-dibenzylethane-1,2-diamine) (L), and its complex with copper acetate was synthesized and characterized by some spectral analyses. The copper(Ⅱ) ion is six-coordinated and exhibites octahedral coordination geometry, the coordination atoms are four nitrogen atoms from two (L) ligands and two carboxyl oxygen atoms from two acetic acid groups, respectively. After studying the interaction of the complex with calf thymus DNA through UV and fluorescence spectra, we can find that there is a strong binding and a large affinity berween the complex and calf thymus DNA. CCDC: 649416.
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