金属学报
金屬學報
금속학보
ACTA METALLURGICA SINICA
2009年
7期
788-800
,共13页
张哲峰%张鹏%田艳中%张青科%屈伸%邹鹤飞%段启强%李守新%王中光
張哲峰%張鵬%田豔中%張青科%屈伸%鄒鶴飛%段啟彊%李守新%王中光
장철봉%장붕%전염중%장청과%굴신%추학비%단계강%리수신%왕중광
晶界%孪晶界%相界%互连界面%疲劳裂纹
晶界%孿晶界%相界%互連界麵%疲勞裂紋
정계%련정계%상계%호련계면%피로렬문
grain boundary%twin boundary%phase boundary%interconnect interface%fatigue cracking
总结了不同金属材料在低周疲劳过程中典型的晶界、孪晶界、相界和微电子互连界面的损伤开裂行为.纯Cu中疲劳裂纹萌生的难易顺序为:小角度晶界、驻留滑移带和大角度晶界.对于纯Cu与铜合金中退火孪晶界,是否萌生疲劳裂纹与合金成分有关,随合金元素的加入降低了层错能,退火孪晶界相对容易萌生疲劳裂纹.对于Cu-Ag二元合金,由于存在不同的晶界和相界面,是否萌生疲劳裂纹取决于界面两侧晶体的取向差,通常两侧取向差大的界面容易萌生疲劳裂纹.在微电子互连界面中,疲劳裂纹萌生位置与焊料成分和时效时间有关,对于Sn-Ag/Cu互连界面,疲劳裂纹通常沿焊料与界面化合物结合处萌生;对于Sn-Bi/Cu互连界面,随时效时间增加会出现明显的由于Bi元素偏聚造成的界面脆性.
總結瞭不同金屬材料在低週疲勞過程中典型的晶界、孿晶界、相界和微電子互連界麵的損傷開裂行為.純Cu中疲勞裂紋萌生的難易順序為:小角度晶界、駐留滑移帶和大角度晶界.對于純Cu與銅閤金中退火孿晶界,是否萌生疲勞裂紋與閤金成分有關,隨閤金元素的加入降低瞭層錯能,退火孿晶界相對容易萌生疲勞裂紋.對于Cu-Ag二元閤金,由于存在不同的晶界和相界麵,是否萌生疲勞裂紋取決于界麵兩側晶體的取嚮差,通常兩側取嚮差大的界麵容易萌生疲勞裂紋.在微電子互連界麵中,疲勞裂紋萌生位置與銲料成分和時效時間有關,對于Sn-Ag/Cu互連界麵,疲勞裂紋通常沿銲料與界麵化閤物結閤處萌生;對于Sn-Bi/Cu互連界麵,隨時效時間增加會齣現明顯的由于Bi元素偏聚造成的界麵脆性.
총결료불동금속재료재저주피로과정중전형적정계、련정계、상계화미전자호련계면적손상개렬행위.순Cu중피로렬문맹생적난역순서위:소각도정계、주류활이대화대각도정계.대우순Cu여동합금중퇴화련정계,시부맹생피로렬문여합금성분유관,수합금원소적가입강저료층착능,퇴화련정계상대용역맹생피로렬문.대우Cu-Ag이원합금,유우존재불동적정계화상계면,시부맹생피로렬문취결우계면량측정체적취향차,통상량측취향차대적계면용역맹생피로렬문.재미전자호련계면중,피로렬문맹생위치여한료성분화시효시간유관,대우Sn-Ag/Cu호련계면,피로렬문통상연한료여계면화합물결합처맹생;대우Sn-Bi/Cu호련계면,수시효시간증가회출현명현적유우Bi원소편취조성적계면취성.
Interfacial fatigue cracking behaviors along large-angle grain boundaries(GBs),twin boundaries(TBs),phase boundaries(PBs)and joint interfaces in metallic materials were summarized.It is found that the resistance to fatigue crack initiation decreases in the order of low-angle GBs.persistent slip bands and the large-angle GBs in pure Cu.For annealing TBs.fatigue cracking initiation strongly depends on the stacking fault energy(SFE)in Cu alloys.With decreasing SFE,fatigue cracking along TBs becomes easy.In Cu-Ag binary alloys,the misorientation across GBs or PBs plays an important role in the fatigue cracking,and large misorientation often makes the final fatigue cracking.For the Cu/solder joint interface,the interfacial fatigue cracking modes are affected by the solders and aging time.In Sn-Ag/Cu solder joints,fatigue crack normally nucleates along the interface between the Sn-Ag solder and the intermetallics compounds(IMCs);however,for Sn-Bi/Cu solder joints,brittle interfacial fatigue cracking always occurs along the interface between Cu and the IMCs due to the Bi segregation after aging for a long time.