无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2009年
2期
364-368
,共5页
铜配位聚合物%柔性硫醚%晶体结构%荧光
銅配位聚閤物%柔性硫醚%晶體結構%熒光
동배위취합물%유성류미%정체결구%형광
copper(Ⅰ) coordination polymer%flexible thioether%crystal structure%photoluminescence
A complex [Cu2Br2(L)2]2 (1) (L=bis (2-pyrimidinylthio)methane) has been synthesized and structurally characterized. Complex 1 contains dinuclear Cu2Br2 units, which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle. The adjacent layers are further connected through interpyrimidyl rings C-H strong green solid-state photoluminescence, due to metal-to-ligand charge-transfer (MLCT) at room temperature. CCDC: 711434.
