CAJ | 학술논문

研究发现许多重要的金属促进的合成反应都是经过金属杂环进行的,因此金属杂环的合成方法学以及反应化学研究受到了学术界及工业界的极大关注.关于金属杂五元环的研究报道数量很多,而金属杂六元环的文献报道非常之少.考虑到金属杂六元环在有机合成化学中潜在的重要用途,结合作者近年的一些研究工作,对目前已经报道的金属杂六元环的合成方法进行回顾与展望.
연구발현허다중요적금속촉진적합성반응도시경과금속잡배진행적,인차금속잡배적합성방법학이급반응화학연구수도료학술계급공업계적겁대관주.관우금속잡오원배적연구보도수량흔다,이금속잡륙원배적문헌보도비상지소.고필도금속잡륙원배재유궤합성화학중잠재적중요용도,결합작자근년적일사연구공작,대목전이경보도적금속잡륙원배적합성방법진행회고여전망.
Preparation and reaction of metallacyclic compounds have attracted increasing interest in recent years, since many synthetically important transition-metal-assisted reactions proceed via metallacyclic in-termediates. Compared with a large number of reports on 5-membered metallacycles, there are only a few reports on 6-membered metallacycles. Because of the potential application of 6-membered metallacycles, a review is given about the preparative methods of six-membered metallacycles developed in our group as well as in other groups.