CAJ | 학술논문

利用拉曼光谱结合X射线衍射物相检测方法,对安徽蚌埠双墩春秋中晚期"钟离君柏"墓出土彩绘陶器颜料的物相结构进行了分析测定.结果表明,陶器表面的红色、黄色和黑色颜料皆保存较好,未发生明显变化,分别是无机矿物朱砂(HgS)和针铁矿(α-FeO(OH))及炭黑.同时,拉曼光谱与X射线衍射分析的结果都显示红色颜料朱砂的组成物相单一,不含天然朱砂的伴生矿物石英,且其晶粒尺寸可能在纳米范围,应是由人工合成或经过古人的加工、纯化处理.针铁矿的发现表明春秋时期该矿物己被用作黄色颜料,这是目前己知的针铁矿作为黄颜料使用的最早的实例.
이용랍만광보결합X사선연사물상검측방법,대안휘방부쌍돈춘추중만기"종리군백"묘출토채회도기안료적물상결구진행료분석측정.결과표명,도기표면적홍색、황색화흑색안료개보존교호,미발생명현변화,분별시무궤광물주사(HgS)화침철광(α-FeO(OH))급탄흑.동시,랍만광보여X사선연사분석적결과도현시홍색안료주사적조성물상단일,불함천연주사적반생광물석영,차기정립척촌가능재납미범위,응시유인공합성혹경과고인적가공、순화처리.침철광적발현표명춘추시기해광물기피용작황색안료,저시목전기지적침철광작위황안료사용적최조적실례.
Based on the analysis of Raman spectroscopy and XRD methods, the structures of different pigments on the painted pottery from the Monarch Bai Tomb of Zhongli State in the middle and late Spring and Autumn period at Shungdun Village, Bengbu City, Anhui Province were analyzed. The result shows that all the pigments, including red, yellow and black pigments, have been well preserved, and these three pigments were identified as cinnabar, goethite and carbon black respectively. Both Raman spectroscopy and XRD analysis show that the crystal composition of red pigments, cinnabar, is very pure without quartz crystal, the associated crystal of natural cinnabar, and at the same time the crystal size of cinnabar is possibly at the nanometer scale It suggests that this red pigments perhaps were a synthetic material or processed and purified by our ancestors. The dis-covery of goethite shows that this mineral has been used as pigments as early as in the Spring and Autumn period. This is the earliest example that goethite was used as yellow pigments.