无机材料学报
無機材料學報
무궤재료학보
JOURNAL OF INORGANIC MATERIALS
2000年
5期
815-821
,共7页
初宝进%李国荣%江向平%陈大任
初寶進%李國榮%江嚮平%陳大任
초보진%리국영%강향평%진대임
(1-x)Na1/2Bi1/2TiO3-xBaTiO3%无铅压电陶瓷%准同型相界%弛豫性相变%过渡相区
(1-x)Na1/2Bi1/2TiO3-xBaTiO3%無鉛壓電陶瓷%準同型相界%弛豫性相變%過渡相區
(1-x)Na1/2Bi1/2TiO3-xBaTiO3%무연압전도자%준동형상계%이예성상변%과도상구
(1-x)Na1/2Bi1/2TiO3-xBaTiO3%lead-free piezoelectric ceramics%morphotropic boundary%relaxation phase transition%transitional phase region
系统研究了(1-x)Na1/2Bi1/2TiO3-xBaTiO3(x=0.02、0.04、0.06、0.08、0.10)无铅压电陶瓷系统的相界、材料压电性能,弛豫特性及相变. 这个系统的陶瓷材料具有Kt/Kp较大,频率常数比较高等特点. X-ray衍射结构?分析发现此系统的相界在0.04<x<0.06之间;材料的一些主要性能在相界附近达到极值. 利用介电系数-温度曲线, 并结合热激电流曲线对此系统的弛豫性进行研究和分析;初步研究了各配方组成的铁电-顺电的相变过程,发现在一定的组成范围内,材料在由铁电相向顺电相的转变过程中经历了一个过渡相区.
繫統研究瞭(1-x)Na1/2Bi1/2TiO3-xBaTiO3(x=0.02、0.04、0.06、0.08、0.10)無鉛壓電陶瓷繫統的相界、材料壓電性能,弛豫特性及相變. 這箇繫統的陶瓷材料具有Kt/Kp較大,頻率常數比較高等特點. X-ray衍射結構?分析髮現此繫統的相界在0.04<x<0.06之間;材料的一些主要性能在相界附近達到極值. 利用介電繫數-溫度麯線, 併結閤熱激電流麯線對此繫統的弛豫性進行研究和分析;初步研究瞭各配方組成的鐵電-順電的相變過程,髮現在一定的組成範圍內,材料在由鐵電相嚮順電相的轉變過程中經歷瞭一箇過渡相區.
계통연구료(1-x)Na1/2Bi1/2TiO3-xBaTiO3(x=0.02、0.04、0.06、0.08、0.10)무연압전도자계통적상계、재료압전성능,이예특성급상변. 저개계통적도자재료구유Kt/Kp교대,빈솔상수비교고등특점. X-ray연사결구?분석발현차계통적상계재0.04<x<0.06지간;재료적일사주요성능재상계부근체도겁치. 이용개전계수-온도곡선, 병결합열격전류곡선대차계통적이예성진행연구화분석;초보연구료각배방조성적철전-순전적상변과정,발현재일정적조성범위내,재료재유철전상향순전상적전변과정중경력료일개과도상구.
For (1-x)Na1/2Bi1/2TiO3-BaTiO3(x=0.02, 0.04, 0.06, 0.08, 0.10) lead-free ceramic system the morphotropic boundary, piezoelectric property, relaxation property and phase transition were investigated. The piezoelectric ceramics ofthis system possess large ratios of Kt/Kp and high frequency constants. According to XRD patterns, the morphotropic boundary lies in the composition range of 0.04<x<0.06. The main physical properties of this system can reach extreme values near the morphotropic boundary. The relaxation property of this system was studied by using dielectric constant-temperature curves and thermally stimulated depolarization current (TSDC) curves. Phase transition from ferroelectric to paraelectric phase was also primarily discussed and it was found out that the ceramics within a composition range possess transitional phase region between ferroelectric phase and paraelectric phase.