稀有金属
稀有金屬
희유금속
CHINESE JOURNAL OF RARE METALS
2009年
6期
889-893
,共5页
武彪%武名麟%臧宏%李岩%华金仓%温建康
武彪%武名麟%臧宏%李巖%華金倉%溫建康
무표%무명린%장굉%리암%화금창%온건강
高海拔%次生硫化铜矿%细菌浸出
高海拔%次生硫化銅礦%細菌浸齣
고해발%차생류화동광%세균침출
high attitude%secondary copper sulfides%bioleaching
温度、 pH、 O_2及CO_2的供给是影响细菌活性的关键因素, 西藏玉龙铜矿地处高原地区, 海拔高、温度低、空气稀薄, 应用生物湿法冶金技术提铜难度较大. 对高海拔地区以次生硫化铜矿为主的硫化铜矿进行了现场生物柱浸扩大试验研究, 选育出耐寒高效浸矿细菌, 考察了不同粒度条件下该矿物的浸出特性, 分析高海拔地区生物浸出的可行性. 结果表明, 选育出的细菌耐受力强, 在极端条件下生长良好, 细菌生长最佳pH范围为1.7~2.0, 浸出体系温度高于5 ℃. 浸出5个月, 浸出过程中氧化还原电位高于800 mV(SHE)以上, 铜的浸出可达75.68%, 应用生物浸出完全可行.
溫度、 pH、 O_2及CO_2的供給是影響細菌活性的關鍵因素, 西藏玉龍銅礦地處高原地區, 海拔高、溫度低、空氣稀薄, 應用生物濕法冶金技術提銅難度較大. 對高海拔地區以次生硫化銅礦為主的硫化銅礦進行瞭現場生物柱浸擴大試驗研究, 選育齣耐寒高效浸礦細菌, 攷察瞭不同粒度條件下該礦物的浸齣特性, 分析高海拔地區生物浸齣的可行性. 結果錶明, 選育齣的細菌耐受力彊, 在極耑條件下生長良好, 細菌生長最佳pH範圍為1.7~2.0, 浸齣體繫溫度高于5 ℃. 浸齣5箇月, 浸齣過程中氧化還原電位高于800 mV(SHE)以上, 銅的浸齣可達75.68%, 應用生物浸齣完全可行.
온도、 pH、 O_2급CO_2적공급시영향세균활성적관건인소, 서장옥룡동광지처고원지구, 해발고、온도저、공기희박, 응용생물습법야금기술제동난도교대. 대고해발지구이차생류화동광위주적류화동광진행료현장생물주침확대시험연구, 선육출내한고효침광세균, 고찰료불동립도조건하해광물적침출특성, 분석고해발지구생물침출적가행성. 결과표명, 선육출적세균내수력강, 재겁단조건하생장량호, 세균생장최가pH범위위1.7~2.0, 침출체계온도고우5 ℃. 침출5개월, 침출과정중양화환원전위고우800 mV(SHE)이상, 동적침출가체75.68%, 응용생물침출완전가행.
Temperature, pH, O_2 and supply of CO_2 were the key influencing factors of bacterial activity, Tibet Yulong copper mining located in high altitude region with low temperature and thin air, so it was very difficult to recovery copper from sulfides by bacterium. This paper focused on the column bioleaching of secondary copper sulfides in high altitude. High efficient bacteria, which could resist low temperature, were cultivated. The leaching characteristics of the mineral were researched under various particle size conditions, and the feasibility of bioleaching copper sulfides in high altitude region was analyzed. The results showed that the cultivated bacteria had high resistance of low temperature, which could grow well under extreme conditions. The proper pH scope was between 1.7 and 2.0, and the temperature was higher than 5 ℃. After leached 5 months, the solution redox potential was above 850 mV(SHE) and the copper recovery rate was as high as 75.68%. It was completely feasible to recovery copper from sulfides in high altitude region by bioleaching.