CAJ | 학술논문

本文报道了一种新的配体:10-乙基-3-甲酰吩噻嗪缩肼基二硫代甲酸甲酯(HL)及其金属配合物的合成.采用了元素分析、质谱、核磁共振、红外光谱对配体及其金属配合物进行了表征.此外,并应用紫外、荧光和Z-扫描技术,测定了配体及其金属配合物的荧光最佳发射波长(λmax em)、荧光量子产率(φf)、寿命(τ)和非线性光学性质.结果表明它们在DMF溶液中都能发射出较强的橄榄色荧光,配体及其金属配合物都有双光子吸收,并且金属配合物的非线性光学效应比配体明显增强.用半经验量子化学方法(RHF/PM3)计算结果与实验值较为吻合.
본문보도료일충신적배체:10-을기-3-갑선분새진축정기이류대갑산갑지(HL)급기금속배합물적합성.채용료원소분석、질보、핵자공진、홍외광보대배체급기금속배합물진행료표정.차외,병응용자외、형광화Z-소묘기술,측정료배체급기금속배합물적형광최가발사파장(λmax em)、형광양자산솔(φf)、수명(τ)화비선성광학성질.결과표명타문재DMF용액중도능발사출교강적감람색형광,배체급기금속배합물도유쌍광자흡수,병차금속배합물적비선성광학효응비배체명현증강.용반경험양자화학방법(RHF/PM3)계산결과여실험치교위문합.
A new ligand, S-methyl-β-N-[ 10-ethylphenothiazine-3-methylene] dithioearbazate (abbreviated as HL) andits complexes ML2(M = Ni, Cu, Zn, Cd and Pd) have been synthesized and characterized by elemental analyses,EI-MS, 1H NMR, IR, UV-vis spectra, photoluminescence measurements. All of the compounds emit an olivinecolor in DMF solution. The emission maxima (λmaxem), fluorescence quantums (φf), and lifetimes (τ) of eachcompound are measured. The nonlinear absorptions of HL and ML2 solutions (in DMF) are measured byopen-aperture Z-sean technique at a 532nm wavelength. Theoretical calculations were consistent with the experi-mental results.