CAJ | 학술논문

本文合成了2-羟基-1-萘甲醛半碳酰腙铬(Ⅲ)单核配合物,通过红外、紫外、荧光光谱和单晶X-射线衍射等方法对其结构进行了表征.其晶体结构属于单斜晶系,空间群C2/c.光谱数据表明:配体2-羟基-1-萘甲醛半碳酰腙作为三齿螯合剂,通过酚氧,亚胺基氮和酮氧与铬(Ⅲ)离子配位.其铬(Ⅲ)中心为扭曲的六配位八面体几何构型.
본문합성료2-간기-1-내갑철반탄선종락(Ⅲ)단핵배합물,통과홍외、자외、형광광보화단정X-사선연사등방법대기결구진행료표정.기정체결구속우단사정계,공간군C2/c.광보수거표명:배체2-간기-1-내갑철반탄선종작위삼치오합제,통과분양,아알기담화동양여락(Ⅲ)리자배위.기락(Ⅲ)중심위뉴곡적륙배위팔면체궤하구형.
The mononuclear chromium(Ⅲ) complex with 2-hydroxy-1-naphthaldehyde semicarbazone was synthesized and characterized by IR, UV-Vis, fluorescence spectra and single-crystal structure determination. The crystal structure belongs to monoclinic system, space group C2/c with a=3.535 7(8) nm, b=1.608 5(4) nm, c=0.930 52(19) nm,β=98.271(4)°, and Z=8. The crystal structure and spectra data suggest that the ligand of 2-hydro-1-naphthal-dehyde semicarbazone behaves as a tridentate chelating agent, coordinating through phenolic oxygen, nitrogen atom of C=N group and ketonic oxygen. The chromium (Ⅲ) center is a six-coordinated distorted octahedral geometry. CCDC: 647892.