四川环境
四川環境
사천배경
2011年
6期
26-29
,共4页
周婷%王德龙%汪廷洪%李科
週婷%王德龍%汪廷洪%李科
주정%왕덕룡%왕정홍%리과
原子吸收%采气废水%镉%氘灯%准确度
原子吸收%採氣廢水%鎘%氘燈%準確度
원자흡수%채기폐수%력%도등%준학도
Atomic absorption%gas production wastewater%cadmium%deuterium lamp%accuracy
在石化行业中,由于采气废水多为高舍盐废水,如果按照地表水、地下水的测试方法对其重金属指标进行测试,其测试结果和真实值之间存在较大的偏差。本研究中采用火焰原子吸收法对影响吸收的背景进行氘灯扣除,得到了一种适合于高含盐废水体中镉含量测定的分析方法。通过实验验证,该方法相对误差在8.75%以内,检测限0.0042mg/L,回收率在93.8%-101%之间,并且重现性良好,能够满足分析测试的要求。
在石化行業中,由于採氣廢水多為高捨鹽廢水,如果按照地錶水、地下水的測試方法對其重金屬指標進行測試,其測試結果和真實值之間存在較大的偏差。本研究中採用火燄原子吸收法對影響吸收的揹景進行氘燈釦除,得到瞭一種適閤于高含鹽廢水體中鎘含量測定的分析方法。通過實驗驗證,該方法相對誤差在8.75%以內,檢測限0.0042mg/L,迴收率在93.8%-101%之間,併且重現性良好,能夠滿足分析測試的要求。
재석화행업중,유우채기폐수다위고사염폐수,여과안조지표수、지하수적측시방법대기중금속지표진행측시,기측시결과화진실치지간존재교대적편차。본연구중채용화염원자흡수법대영향흡수적배경진행도등구제,득도료일충괄합우고함염폐수체중력함량측정적분석방법。통과실험험증,해방법상대오차재8.75%이내,검측한0.0042mg/L,회수솔재93.8%-101%지간,병차중현성량호,능구만족분석측시적요구。
In petrochemical industry, the gas production wastewater usually contains high content of salt. It will disturb the determination of heavy metals resulting in a deviate from the real value if the determination adopting the method for ground water and surface water. In this paper, a novel determination method for cadmium was developed by adopting the Atomic Absorption Spectrometry to subtract the background through using the deuterium lamp, which was suitable to determine the cadmium content in high salt wastewater. Experiments confirmed that the relative error was less than 8.75% and the detection limit was 0. 0042 mg/L with recovery of 93. 8% -101%. The repeatability was high enough to meet the requirement of determination.