CAJ | 학술논문

报道了高压下非线性光学晶体KNbO3(KN),KIO3(KI)和KTiOAsO4(KTA)的Raman散射研究结果,压力引起的Raman光谱非常丰富,在所有的样品中都观察到了压致相变.另外,在KN晶体中发现了非常强的压致振动耦合现象及高压非晶相.对于KTA,建立了Raman光谱变化与其倍频效率随压力提高之间的可能联系.在22GPa以上,KI晶体的基本组成集团可能由IO3变为IO6.
보도료고압하비선성광학정체KNbO3(KN),KIO3(KI)화KTiOAsO4(KTA)적Raman산사연구결과,압력인기적Raman광보비상봉부,재소유적양품중도관찰도료압치상변.령외,재KN정체중발현료비상강적압치진동우합현상급고압비정상.대우KTA,건립료Raman광보변화여기배빈효솔수압력제고지간적가능련계.재22GPa이상,KI정체적기본조성집단가능유IO3변위IO6.
In this presentation,we report on the high-pressure Raman spectroscopic studies of some non-linear optical crystals,e.g.KNbO3(KN),KIO3(KI) and KTiOAsO4(KTA),which are important for both their practical applications and theoretical values.The effect of pressure on KN is extremely large and there exist a rich variety of pressure-induced changes.Mode softening is found for some of the characteristic Raman bands.Intensity transfer and frequency repelling have been observed in the 200cm-1 region as a result of strong coupling between two B1(TO)modes,whose frequencies have been brought closer under pressure.There are three new crystalline and an amorphous phases,and two of the phase transitions are of displacive type.Three first-order pressure-induced phase transitions are inferred for KTA.The first takes place at 3.2GPa,indicated by drastic spectral changes related to TiO6 octahedra.The second occurs at 7.5GPa involving both TiO6 and AsO4 groups.Several modes belonging to TiO6 also soften between 0～7.5GPa.The third phase transition occurs near 10GPa and the high-pressure phase should be of higher symmetry.Drastic spectral changes and phase transitions are observed for KI up to 32GPa.The first transition occurs at 5.0GPa characterised by major spectral changes of the ν1,ν2,and ν4 modes.The other transitions are found at 8.7,15 and 22GPa.The phase that is stable between 15～22GPa has a higher symmetry than the phases in the lower pressures.The IO3 pyramidal ions may have lost their identity and changed to IO6 octahedra above 22GPa.