CAJ | 학술논문

合成了2,9,16,23-四羧基金属酞菁锌(Zn-taPc),用紫外-可见光谱和红外光谱对其进行了表征.测试了其在乙醇溶剂中的荧光光谱,在356nm的紫外光激发下,Zn-taPc在456nm附近出现发射峰.发现了碘的乙醇溶液对其有荧光猝灭现象,并进行了初步分析.
합성료2,9,16,23-사최기금속태정자(Zn-taPc),용자외-가견광보화홍외광보대기진행료표정.측시료기재을순용제중적형광광보,재356nm적자외광격발하,Zn-taPc재456nm부근출현발사봉.발현료전적을순용액대기유형광졸멸현상,병진행료초보분석.
Zn(Ⅱ)-2,9,16,23-tetracarboxyphthalocyanine was synthesized, andconfirmed by Uv-Vis and Infrared spectra. The fluorescence spectra of in ethanol have been studied. An emission peak near 456 nm was obtained when the solution was excited with 356 nm ultraviolet light. The fluorescence of Zn-taPc was quenched significantly by adding I2 to the solution due to the formation of a charge transfer complex in the excited state between Zn-taPc and I2.